化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
2期
628-632
,共5页
董飞英%李旦洋%张良%范利武%徐旭%俞自涛%胡亚才
董飛英%李旦洋%張良%範利武%徐旭%俞自濤%鬍亞纔
동비영%리단양%장량%범리무%서욱%유자도%호아재
氧化石墨烯%水悬浮液%淬火沸腾%临界热通量%表面沉积
氧化石墨烯%水懸浮液%淬火沸騰%臨界熱通量%錶麵沉積
양화석묵희%수현부액%쉬화비등%림계열통량%표면침적
graphene oxide nanosheets%aqueous suspensions%quenching boiling%critical heat flux%surface deposition
采用淬火法对质量分数为0.002%的氧化石墨烯水悬浮液的瞬态沸腾特性进行了表征。通过对三种代表性工况的对比分析研究了氧化石墨烯在沸腾表面的沉积对淬火沸腾过程的影响。由于氧化石墨烯在过渡沸腾阶段的沉积,水悬浮液的淬火过程较之去离子水缩短了约10 s,临界热通量则提升了约10%,对应的表面接触角从104°减小到78°。将已沉积表面再次在去离子水中淬火后,表面接触角回升到89°,临界热通量则有所回落。结果表明,氧化石墨烯的表面沉积虽然是强化临界热通量的决定性因素,但淬火过程的速率和过渡沸腾阶段的传热速率还受到氧化石墨烯的动态沉积过程和水悬浮液中悬浮氧化石墨烯的共同影响。
採用淬火法對質量分數為0.002%的氧化石墨烯水懸浮液的瞬態沸騰特性進行瞭錶徵。通過對三種代錶性工況的對比分析研究瞭氧化石墨烯在沸騰錶麵的沉積對淬火沸騰過程的影響。由于氧化石墨烯在過渡沸騰階段的沉積,水懸浮液的淬火過程較之去離子水縮短瞭約10 s,臨界熱通量則提升瞭約10%,對應的錶麵接觸角從104°減小到78°。將已沉積錶麵再次在去離子水中淬火後,錶麵接觸角迴升到89°,臨界熱通量則有所迴落。結果錶明,氧化石墨烯的錶麵沉積雖然是彊化臨界熱通量的決定性因素,但淬火過程的速率和過渡沸騰階段的傳熱速率還受到氧化石墨烯的動態沉積過程和水懸浮液中懸浮氧化石墨烯的共同影響。
채용쉬화법대질량분수위0.002%적양화석묵희수현부액적순태비등특성진행료표정。통과대삼충대표성공황적대비분석연구료양화석묵희재비등표면적침적대쉬화비등과정적영향。유우양화석묵희재과도비등계단적침적,수현부액적쉬화과정교지거리자수축단료약10 s,림계열통량칙제승료약10%,대응적표면접촉각종104°감소도78°。장이침적표면재차재거리자수중쉬화후,표면접촉각회승도89°,림계열통량칙유소회락。결과표명,양화석묵희적표면침적수연시강화림계열통량적결정성인소,단쉬화과정적속솔화과도비등계단적전열속솔환수도양화석묵희적동태침적과정화수현부액중현부양화석묵희적공동영향。
The transient boiling of an aqueous suspension with graphene oxide nanosheets (GONs), at a mass fraction of 0.002%, was characterized using the quenching method. The effects of GONs deposited on the boiling surface were compared among three representative cases. With the deposition of GONs during the transition boiling phase, the quenching period of the suspension was shortened by 10 s as compared to that of deionized water, while the critical heat flux (CHF) was improved by 10%and the contact angle was reduced from 104° to 78°. After subsequent quenching of the boiling surface with GON deposition in deionized water, the contact angle was increased to 89° and the CHF was somewhat deteriorated. It was concluded that the enhancement of CHF is primarily resulted from surface deposition of GONs. The quenching speed and the heat transfer rate during the transition boiling phase are also affected by the dynamic deposition process and the suspended GONs.