针织工业
針織工業
침직공업
KNITTING INDUSTRIES
2013年
9期
38-42
,共5页
壳聚糖%季铵盐改性%大豆蛋白复合纤维%无盐染色%上染率%水洗色牢度
殼聚糖%季銨鹽改性%大豆蛋白複閤纖維%無鹽染色%上染率%水洗色牢度
각취당%계안염개성%대두단백복합섬유%무염염색%상염솔%수세색뇌도
Chitosan%Quaternized Modification%Soybean Protein Composite Fibers%Dyeing without Salt%Dye Uptake%Washing Fastness
利用双氧水氧化降解壳聚糖,以2,3-环氧丙基三甲基氯化铵为改性剂,对氧化降解后的低分子量壳聚糖进行季铵化改性,得到壳聚糖季铵盐(HTCC),利用HTCC对大豆蛋白复合纤维改性后进行无盐染色,并与传统染色工艺进行对比分析。红外光谱曲线表明己经有效合成了HTCC;实验结果显示,季铵化改性后可以大大提高壳聚糖的水溶性,取代度达到90%左右;另外发现,HTCC在温度90℃、浓度8 g/L条件下浸渍处理大豆蛋白复合纤维10 min,可获得最佳的预处理效果;经HTCC改性的大豆蛋白复合纤维织物在染色中可以降低盐的用量,且无盐染色织物水洗色牢度与传统染色工艺的相当。
利用雙氧水氧化降解殼聚糖,以2,3-環氧丙基三甲基氯化銨為改性劑,對氧化降解後的低分子量殼聚糖進行季銨化改性,得到殼聚糖季銨鹽(HTCC),利用HTCC對大豆蛋白複閤纖維改性後進行無鹽染色,併與傳統染色工藝進行對比分析。紅外光譜麯線錶明己經有效閤成瞭HTCC;實驗結果顯示,季銨化改性後可以大大提高殼聚糖的水溶性,取代度達到90%左右;另外髮現,HTCC在溫度90℃、濃度8 g/L條件下浸漬處理大豆蛋白複閤纖維10 min,可穫得最佳的預處理效果;經HTCC改性的大豆蛋白複閤纖維織物在染色中可以降低鹽的用量,且無鹽染色織物水洗色牢度與傳統染色工藝的相噹。
이용쌍양수양화강해각취당,이2,3-배양병기삼갑기록화안위개성제,대양화강해후적저분자량각취당진행계안화개성,득도각취당계안염(HTCC),이용HTCC대대두단백복합섬유개성후진행무염염색,병여전통염색공예진행대비분석。홍외광보곡선표명기경유효합성료HTCC;실험결과현시,계안화개성후가이대대제고각취당적수용성,취대도체도90%좌우;령외발현,HTCC재온도90℃、농도8 g/L조건하침지처리대두단백복합섬유10 min,가획득최가적예처리효과;경HTCC개성적대두단백복합섬유직물재염색중가이강저염적용량,차무염염색직물수세색뇌도여전통염색공예적상당。
After chitosan degraded by hydrogen peroxide, chitosan quaternary ammonium salt(HTCC) is made with 2,3 epoxypropyl trimethyl ammonium chloride existing, which is used as modifier agent for quaternized modification. Then soybean protein composite fibers are pretreated by HTCC, the dyeing processes without salts of it are ana-lyzed, compared with traditional dyeing process of common soybean protein composite fibers. The results from in-frared spectrum curve proves that HTCC are composed effectively; it is also found that after quaternized modifica-tion, the water-solubility of chitosan are improved obviously and the degree of substitution can reach about 90%. The optimum conditions for soybean protein composite fibers pretreatment by HTCC are: 8 g/L of HTCC treat fibers under 90 ℃ for 10 minutes. The results also show that after soybean protein composite fibers pretreated by HTCC, dosage of salts in dyeing process can be decreased; meanwhile, the washing fastness that dyeing without salts is the same with that of traditional dyeing process.