CAJ | 학술논문

为了评价植烟土壤中常用3种除草剂对生态环境的安全性，建立了同时测定植烟土壤和水中高效氟吡甲禾灵、精吡氟禾草灵和精喹禾灵3种除草剂残留量的高效液相色谱分析方法。水中3种农药残留用二氯甲烷-丙酮（20：1，v：v）混合液提取，土壤中农药残留用丙酮提取，经弗罗里硅土净化后，采用HPLC法外标法定量。结果表明，3种除草剂在0.0050～5.0 mg/L范围内线性良好，相关系数均在0.99以上；土壤中添加水平在0.050～1.0 mg/kg时，3种除草剂在土壤中平均添加回收率为77.5%～110.3%，相对偏差为1.6%～10.2%，当水中添加水平在0.0050～1.0 mg/L时，回收率为88.9%～101.2%，相对偏差为0.9%～8.2%，符合农药残留分析方法要求。
위료평개식연토양중상용3충제초제대생태배경적안전성，건립료동시측정식연토양화수중고효불필갑화령、정필불화초령화정규화령3충제초제잔류량적고효액상색보분석방법。수중3충농약잔류용이록갑완-병동（20：1，v：v）혼합액제취，토양중농약잔류용병동제취，경불라리규토정화후，채용HPLC법외표법정량。결과표명，3충제초제재0.0050～5.0 mg/L범위내선성량호，상관계수균재0.99이상；토양중첨가수평재0.050～1.0 mg/kg시，3충제초제재토양중평균첨가회수솔위77.5%～110.3%，상대편차위1.6%～10.2%，당수중첨가수평재0.0050～1.0 mg/L시，회수솔위88.9%～101.2%，상대편차위0.9%～8.2%，부합농약잔류분석방법요구。
In order to evaluate the bio-environmental safety of three kinds of herbicides, which were often applied to tobacco soil, an analytical method was established to simultaneously determine the residues of haloxyfop-p-methyl, fluazifop-p-butyl and quizafop-p-ethyl in soil and water in tobacco planting field by high performance liquid chromatography. The residues in water was extracted with mixed solution of methylene chloride-acetone (20:1, v:v). The soil was extracted with acetone and the extract was cleaned up by a Florisil chromatography column. The quantification was performed by external standard. The linearity was satisfied (r>0.99) in concentration range of 0.0050-5.0 mg/L. The average recoveries of this three herbicides varied from 77.5%to 110.3%with relative standard deviation of 1.6%-10.2%, when three kinds of herbicides were spiked at 0.050-1.0 mg/kg level in soil. The average recoveries of the three herbicides varied from 88.9%to 101.2%, with relative standard deviation of 0.9%-8.2%, when three kinds of herbicides were spiked at 0.0050-1.0 mg/L level in water. The method in this study could meet the requirements of pesticide residue analysis criteria.