光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2013年
11期
3147-3150
,共4页
刘鹤贺%刘志国%孙天希%彭松%赵为刚%孙蔚渊%李玉德%林晓燕%赵广翠%罗萍%丁训良
劉鶴賀%劉誌國%孫天希%彭鬆%趙為剛%孫蔚淵%李玉德%林曉燕%趙廣翠%囉萍%丁訓良
류학하%류지국%손천희%팽송%조위강%손위연%리옥덕%림효연%조엄취%라평%정훈량
共聚焦微束X射线荧光%毛细管X光透镜%头发%元素分布
共聚焦微束X射線熒光%毛細管X光透鏡%頭髮%元素分佈
공취초미속X사선형광%모세관X광투경%두발%원소분포
Confocal micro X-ray fluorescence%Polycapillary X-ray lens%Hair%Element distribution
头发中的元素与人的饮食和健康状况有关,对头发中元素的分析,不仅可用于刑事物证鉴别,还可为疾病的预防和治疗提供依据,因此,如何检测头发中元素分布等信息倍受人们关注。本文利用基于毛细管X光透镜和实验室普通X射线光源的共聚焦微束X射线荧光技术对单根头进行了无损扫描分析,分析了单根头发中元素的空间分布。在该毛细管X光透镜共聚焦微束X射线荧光技术中,毛细管X光会聚透镜的出口焦斑和毛细管X光平行束透镜的入口焦斑处在共聚焦状态,从而形成共聚焦微元,探测器只能探测到来自该共聚焦微元中的X射线信号,降低了背底信号对X射线荧光谱的影响,从而有利于提高该共聚焦X射线荧光技术的分析精度。该共聚焦技术中采用了具有高功率密度增益的毛细管X光会聚透镜,降低了该共聚焦X射线荧光技术对X射线光源功率的要求,从而保证了该共聚焦技术可以采用实验室普通X射线光源,降低了实验成本。实验表明,毛细管X光透镜共聚焦微束X射线荧光技术在单根头发元素分布检测中具有应用价值。
頭髮中的元素與人的飲食和健康狀況有關,對頭髮中元素的分析,不僅可用于刑事物證鑒彆,還可為疾病的預防和治療提供依據,因此,如何檢測頭髮中元素分佈等信息倍受人們關註。本文利用基于毛細管X光透鏡和實驗室普通X射線光源的共聚焦微束X射線熒光技術對單根頭進行瞭無損掃描分析,分析瞭單根頭髮中元素的空間分佈。在該毛細管X光透鏡共聚焦微束X射線熒光技術中,毛細管X光會聚透鏡的齣口焦斑和毛細管X光平行束透鏡的入口焦斑處在共聚焦狀態,從而形成共聚焦微元,探測器隻能探測到來自該共聚焦微元中的X射線信號,降低瞭揹底信號對X射線熒光譜的影響,從而有利于提高該共聚焦X射線熒光技術的分析精度。該共聚焦技術中採用瞭具有高功率密度增益的毛細管X光會聚透鏡,降低瞭該共聚焦X射線熒光技術對X射線光源功率的要求,從而保證瞭該共聚焦技術可以採用實驗室普通X射線光源,降低瞭實驗成本。實驗錶明,毛細管X光透鏡共聚焦微束X射線熒光技術在單根頭髮元素分佈檢測中具有應用價值。
두발중적원소여인적음식화건강상황유관,대두발중원소적분석,불부가용우형사물증감별,환가위질병적예방화치료제공의거,인차,여하검측두발중원소분포등신식배수인문관주。본문이용기우모세관X광투경화실험실보통X사선광원적공취초미속X사선형광기술대단근두진행료무손소묘분석,분석료단근두발중원소적공간분포。재해모세관X광투경공취초미속X사선형광기술중,모세관X광회취투경적출구초반화모세관X광평행속투경적입구초반처재공취초상태,종이형성공취초미원,탐측기지능탐측도래자해공취초미원중적X사선신호,강저료배저신호대X사선형광보적영향,종이유리우제고해공취초X사선형광기술적분석정도。해공취초기술중채용료구유고공솔밀도증익적모세관X광회취투경,강저료해공취초X사선형광기술대X사선광원공솔적요구,종이보증료해공취초기술가이채용실험실보통X사선광원,강저료실험성본。실험표명,모세관X광투경공취초미속X사선형광기술재단근두발원소분포검측중구유응용개치。
The confocal micro X-ray fluorescence (XRF) based on polycapillary X-ray lens and conventional X-ray source was used to carry out the scanning analysis of the distribution of the elements in a single hair .The elemental distribution in the single hair was obtained .In the confocal micro XRF technology ,the output focal spot of the polycapillary focusing X-ray lens and the input focal spot of the polycapillary parallel X-ray lens were adjusted confocally .The detector could only detect the X-rays from the overlapping foci .This confocal structure decreased the effects of the background on the X-ray spectra ,and was accordingly helpful for improving the accuracy of this XRF technology .A polycapillary focusing X-ray lens with a high gain in power density was used to decrease the requirement of power of the X-ray source used in this confocal technology ,and made it possible to per-form such confocal micro XRF analysis by using the conventional X-ray source with low cost .Experimental results indicated that the confocal micro X-ray fluorescence based on polycapillary X-ray lens had potential applications in analyzing the elemental dis-tribution of individual hairs .