有机硅材料
有機硅材料
유궤규재료
SILICONE MATERIAL
2014年
4期
267-271
,共5页
屈裴%杨鑫波%熊婷%车国勇%黄强%尚文翰
屈裴%楊鑫波%熊婷%車國勇%黃彊%尚文翰
굴배%양흠파%웅정%차국용%황강%상문한
甲醇%脱醇型%硅橡胶%贮存稳定性%室温硫化
甲醇%脫醇型%硅橡膠%貯存穩定性%室溫硫化
갑순%탈순형%규상효%저존은정성%실온류화
methanol%dealcoholized%silicone rubber%storages stability%RTV
通过添加无水甲醇模拟脱醇型单组分室温硫化( RTV-1)硅橡胶生产过程中产生的甲醇,研究了甲醇对脱醇型RTV-1硅橡胶性能的影响。结果表明:在配制脱醇型RTV-1硅橡胶时,甲醇的加入对密封胶力学和粘接性能无影响,但会影响部分施工性能。经70℃加速贮存5天后(相当于室温放置6个月),甲醇的存在会导致表干时间延长,力学强度和粘接性能均有一定幅度的下降;当甲醇质量分数为1%时,脱醇型RTV-1硅橡胶不硫化;若控制配制时甲醇的残留质量分数低于0.25%,则在加速贮存后,脱醇型RTV-1硅橡胶的施工性能略有下降,力学性能与粘接性能保持率达到80%以上。
通過添加無水甲醇模擬脫醇型單組分室溫硫化( RTV-1)硅橡膠生產過程中產生的甲醇,研究瞭甲醇對脫醇型RTV-1硅橡膠性能的影響。結果錶明:在配製脫醇型RTV-1硅橡膠時,甲醇的加入對密封膠力學和粘接性能無影響,但會影響部分施工性能。經70℃加速貯存5天後(相噹于室溫放置6箇月),甲醇的存在會導緻錶榦時間延長,力學彊度和粘接性能均有一定幅度的下降;噹甲醇質量分數為1%時,脫醇型RTV-1硅橡膠不硫化;若控製配製時甲醇的殘留質量分數低于0.25%,則在加速貯存後,脫醇型RTV-1硅橡膠的施工性能略有下降,力學性能與粘接性能保持率達到80%以上。
통과첨가무수갑순모의탈순형단조분실온류화( RTV-1)규상효생산과정중산생적갑순,연구료갑순대탈순형RTV-1규상효성능적영향。결과표명:재배제탈순형RTV-1규상효시,갑순적가입대밀봉효역학화점접성능무영향,단회영향부분시공성능。경70℃가속저존5천후(상당우실온방치6개월),갑순적존재회도치표간시간연장,역학강도화점접성능균유일정폭도적하강;당갑순질량분수위1%시,탈순형RTV-1규상효불류화;약공제배제시갑순적잔류질량분수저우0.25%,칙재가속저존후,탈순형RTV-1규상효적시공성능략유하강,역학성능여점접성능보지솔체도80%이상。
Adding various amounts of anhydrous methanol instead of methanol in the preparation of deal -coholized one-component room temperature vulcanizing ( RTV-1 ) silicone rubber , the performance of RTV-1 silicone rubber affected by methanol were investigated .Results showed that in the preparation of dealcoholized RTV-1 sealant , the addition of methanol had little influence on the mechanical properties and adhesion except the construction performance .Accelerated storage after 5 days at 70℃( equivalent to place at room tempera-ture for 6 months) , the mechanical properties , adhesion and construction performances of dealcoholized RTV-1 rubber deteriorated with increasing methanol content .Controlling the residual methanol below 0.25%after accelerating the storage , the construction performances of dealcoholized RTV-1 rubber slightly deteriorated a little, but its mechanic and adhesive properties retained above 80%.