CAJ | 학술논문

重点分析了ZrO2的热性质、化学稳定性和其理论基础。 ZrO2的导热系数极低，可用于热障涂层，介绍了热障涂层的结构和制备方法，说明了 ZrO2作为热障涂层材料的优异特性。分析了ZrO2的表面能与表面酸性强度，表面酸位来源、固体超强酸的原理、性质、制备方法和应用领域。ZrO2的化学稳定性好，可作为催化剂材料基体， ZrO2基催化材料分类为纯 ZrO2催化剂、负载型催化剂和复合型催化剂，列举了ZrO2基固体超强酸的反应方程式， ZrO2复合型催化剂具有更好的催化性能，论述了以CeO2-ZrO2固溶体作为三效催化剂的机理和进展。相关方法和原理可为 ZrO2的热学性质研究提供系统的理论知识，将有助于理解和应用 ZrO2的催化原理和表面性质。
중점분석료ZrO2적열성질、화학은정성화기이론기출。 ZrO2적도열계수겁저，가용우열장도층，개소료열장도층적결구화제비방법，설명료 ZrO2작위열장도층재료적우이특성。분석료ZrO2적표면능여표면산성강도，표면산위래원、고체초강산적원리、성질、제비방법화응용영역。ZrO2적화학은정성호，가작위최화제재료기체， ZrO2기최화재료분류위순 ZrO2최화제、부재형최화제화복합형최화제，열거료ZrO2기고체초강산적반응방정식， ZrO2복합형최화제구유경호적최화성능，논술료이CeO2-ZrO2고용체작위삼효최화제적궤리화진전。상관방법화원리가위 ZrO2적열학성질연구제공계통적이론지식，장유조우리해화응용 ZrO2적최화원리화표면성질。
Thermal properties, chemical stability of ZrO2 and their mechanisms are reviewed.The ultra-low thermal con-ducting coefficient of ZrO2 is the key for its application in thermal barrier coatings , the structure and synthesis methodology are introduced, and advantages of ZrO2 based thermal barrier coatings are described.The surface energy, acidic positions and their originations in ZrO2 , the principle, nature, preparation and application areas of ZrO2 based super-acids are ana-lyzed.The fairly good chemical stability of ZrO2 is the basic for catalytic application.ZrO2 based catalysts can be classi-fied into pure ZrO2 , loaded and composite ones.The composites-based ZrO2 has better catalytic performance and some typical catalytic reactions are also listed.Mechanisms and research progress of CeO2 -ZrO2 solid solutions as three way catalysts are also introduced.This review provides the systematic knowledge of thermal and catalytic applications of ZrO 2 , which can help understanding their mechanisms and surface properties .