CAJ | 학술논문

应用气相色谱/质谱法对2,2,4-三甲基-1,3-戊二醇单异丁酸酯异构体进行分析和鉴定，由电子轰击质谱（EI-MS）获得其特征碎片离子数据，进而对2,2,4-三甲基-1,3-戊二醇单异丁酸酯异构体可能的质谱裂解途径和特征碎片离子进行推导分析，确定2,2,4-三甲基-1,3-戊二醇单异丁酸酯异构体质谱图，并利用结构相似化合物进行了确认，为乳胶漆成膜助剂检测提供可靠依据。
응용기상색보/질보법대2,2,4-삼갑기-1,3-무이순단이정산지이구체진행분석화감정，유전자굉격질보（EI-MS）획득기특정쇄편리자수거，진이대2,2,4-삼갑기-1,3-무이순단이정산지이구체가능적질보렬해도경화특정쇄편리자진행추도분석，학정2,2,4-삼갑기-1,3-무이순단이정산지이구체질보도，병이용결구상사화합물진행료학인，위유효칠성막조제검측제공가고의거。
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate isomers were analyzed and identified by gas chromatography/mass spectrometry. The method has applied electron impact mass spectrometry (EI-MS)to obtain the characteristic fragment ion data, and determine the physical spectrum of 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate isomers by further analysis of the possible fragmentation pathways and characteristic fragment ion of 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate isomers, and use structurally similar compounds for confirm-ing, which provide reliable basis for paint coalescent testing.