稀土学报(英文版)
稀土學報(英文版)
희토학보(영문판)
JOURNAL OF RARE EARTHS
2014年
8期
727-732
,共6页
吴江%张国梁%刘杰%高蕻冰%宋春香%杜浩然%张丽%巩忠萍%吕玉光
吳江%張國樑%劉傑%高蕻冰%宋春香%杜浩然%張麗%鞏忠萍%呂玉光
오강%장국량%류걸%고홍빙%송춘향%두호연%장려%공충평%려옥광
inorganic nanomaterials%samarium/silver/titanium dioxide%photocatalytic%antibacterial activities%rare earths
An inorganic nanomaterials combination of Sm, Ag, and TiO2 was synthesized using supercritical fluid drying (SCFD) combined with sol-gel techniques. The structure, photocatalysis and bacteriostatic activity of the materials were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XRPS), photocatalytic performance, and antibacterial activity experiments. The XRD results showed that the average particle diameter of Sm/Ag/TiO2 was 14.62 nm and Ag and Sm ions were dispersed on the surface of TiO2 in a highly dispersed, amorphous form. The TEM im-age showed that the size of the particle was 12 nm using the scherer formula. The XPS result showed that the element Sm was doped and Ag was loaded inorganic nanomaterials successfully. Sm/Ag/TiO2 exhibited optimal photocatalytic properties at 600 oC, the photocatalytic optimal proportion of Sm/Ag/TiO2 was 2:2:100. When the molar ratio was 2:2:100, the bacteriostatic cir-cle diameter was 16 mm for Staphylococcus aureus, the minimum bacteriostatic concentration was 200μg/mL for white beads coccus, and the minimum bactericidal concentration was 2×104μg/mL for white beads coccus. The SEM results showed that the antibacterial material attached to the candida albicans cell surface, cells appeared fold deformation. Therefore the inorganic nanomaterials Sm/Ag/TiO2 had high temperature resistance, good photocatalytic and antibacterial characteristics in visible light.