CAJ | 학술논문

分别采用DQ型和BC-MS型Ziegler-Natta催化剂催化丙烯本体聚合，助催化剂为三乙基铝（TEAL）与三异丁基铝（TiBA）的混合物，外给电子体为二苯基二甲氧基硅烷，氢气作相对分子质量调节剂，反应釜内的装料系数为70%。首先在20℃条件下进行预聚合，预聚合结束后迅速升温至70℃聚合。研究了TEAL/TiBA混合助催化剂对聚丙烯（PP）等规指数、熔体流动速率（MFR）和力学性能的影响。结果表明：随着助催化剂中TiBA用量的增加，所制PP的等规指数降低，MFR呈降低趋势。与BC-MS型催化剂相比，用DQ型催化剂制备的PP的弯曲强度和弯曲模量总体上较低，简支梁缺口冲击强度相对较高。
분별채용DQ형화BC-MS형Ziegler-Natta최화제최화병희본체취합，조최화제위삼을기려（TEAL）여삼이정기려（TiBA）적혼합물，외급전자체위이분기이갑양기규완，경기작상대분자질량조절제，반응부내적장료계수위70%。수선재20℃조건하진행예취합，예취합결속후신속승온지70℃취합。연구료TEAL/TiBA혼합조최화제대취병희（PP）등규지수、용체류동속솔（MFR）화역학성능적영향。결과표명：수착조최화제중TiBA용량적증가，소제PP적등규지수강저，MFR정강저추세。여BC-MS형최화제상비，용DQ형최화제제비적PP적만곡강도화만곡모량총체상교저，간지량결구충격강도상대교고。
In this paper, two kinds of commercialized Ziegler-Natta catalysts, namely DQ catalyst and BC-MS catalyst, were used to catalyze propylene bulk polymerization with triethylaluminum(TEAL) and triisobutylal-uminium (TiBA) mixtures as cocatalysts, diphenyldimethoxysilane as an external donor and hydrogen as a relative molecular mass regulator, and the charge coefficient of the autoclave was 70%. The prepolymerization of propylene was carried out at 20 ℃,and the temperature was rapidly elevated to 70 ℃ after prepolymerization. The effects of TEAL/TiBA mixed cocatalyst on isotacticity, melt flow rate(MFR) and mechanical properties of the resultant polypropylene(PP) were studied. The results indicate that both the isotacticity and the MFR of the PP tend to decrease as the amount of TiBA in TEAL/TiBA mixed cocatalyst increases. Compared with BC-MS catalyst, the PP prepared with DQ catalyst has lower flexural strength and flexural modulus but higher charpy notched impact strength.