后勤工程学院学报
後勤工程學院學報
후근공정학원학보
JOURNAL OF LOGISTICAL ENGINEERING UNIVERSITY
2014年
2期
46-51,70
,共7页
仙光%龙向宇%方振东%唐然
仙光%龍嚮宇%方振東%唐然
선광%룡향우%방진동%당연
SRT%污泥絮体%磷酸盐形态%动态变化%胞外聚合物
SRT%汙泥絮體%燐痠鹽形態%動態變化%胞外聚閤物
SRT%오니서체%린산염형태%동태변화%포외취합물
solid retention time%sludge floc%phosphate species%dynamic change%extracellular polymer substances
以污泥龄(SRT)为10 d和30 d的2组A/O-SBR反应器活性污泥为研究对象,探讨了SRT对污泥絮体中磷酸盐形态及其动态变化的影响。结果表明,污泥絮体中的磷主要分布于胞外聚合物(EPS),EPS磷占污泥絮体磷总质量的69.45%~73.36%。正磷酸盐( PO3-4-P)、低分子量聚磷酸盐(LMW Poly-P)和高分子量聚磷酸盐(HMW Poly-P)是污泥絮体磷的主要形态。高SRT(30 d)污泥絮体EPS磷含量明显大于中SRT(10 d),表现为前者较后者有更高的PO3-4-P和HMW Poly-P含量,对应着高SRT(30 d)污泥絮体较中SRT(10 d)有更高的磷含量,前者约为后者的1.37倍。厌氧/好氧反应过程中,中SRT (10 d)污泥絮体EPS磷的厌氧降低量和好氧升高量分别为高SRT(30 d)的1.35倍和1.46倍,主要归因于前者的PO3-4-P和HMW Poly-P较后者有更大的厌氧降低量,而PO3-4-P, LMW Poly-P和HMW Poly-P较后者有更大的好氧升高量,对应着中SRT(10 d)污泥絮体较高SRT(30 d)有更强的厌氧释磷和好氧吸磷能力。
以汙泥齡(SRT)為10 d和30 d的2組A/O-SBR反應器活性汙泥為研究對象,探討瞭SRT對汙泥絮體中燐痠鹽形態及其動態變化的影響。結果錶明,汙泥絮體中的燐主要分佈于胞外聚閤物(EPS),EPS燐佔汙泥絮體燐總質量的69.45%~73.36%。正燐痠鹽( PO3-4-P)、低分子量聚燐痠鹽(LMW Poly-P)和高分子量聚燐痠鹽(HMW Poly-P)是汙泥絮體燐的主要形態。高SRT(30 d)汙泥絮體EPS燐含量明顯大于中SRT(10 d),錶現為前者較後者有更高的PO3-4-P和HMW Poly-P含量,對應著高SRT(30 d)汙泥絮體較中SRT(10 d)有更高的燐含量,前者約為後者的1.37倍。厭氧/好氧反應過程中,中SRT (10 d)汙泥絮體EPS燐的厭氧降低量和好氧升高量分彆為高SRT(30 d)的1.35倍和1.46倍,主要歸因于前者的PO3-4-P和HMW Poly-P較後者有更大的厭氧降低量,而PO3-4-P, LMW Poly-P和HMW Poly-P較後者有更大的好氧升高量,對應著中SRT(10 d)汙泥絮體較高SRT(30 d)有更彊的厭氧釋燐和好氧吸燐能力。
이오니령(SRT)위10 d화30 d적2조A/O-SBR반응기활성오니위연구대상,탐토료SRT대오니서체중린산염형태급기동태변화적영향。결과표명,오니서체중적린주요분포우포외취합물(EPS),EPS린점오니서체린총질량적69.45%~73.36%。정린산염( PO3-4-P)、저분자량취린산염(LMW Poly-P)화고분자량취린산염(HMW Poly-P)시오니서체린적주요형태。고SRT(30 d)오니서체EPS린함량명현대우중SRT(10 d),표현위전자교후자유경고적PO3-4-P화HMW Poly-P함량,대응착고SRT(30 d)오니서체교중SRT(10 d)유경고적린함량,전자약위후자적1.37배。염양/호양반응과정중,중SRT (10 d)오니서체EPS린적염양강저량화호양승고량분별위고SRT(30 d)적1.35배화1.46배,주요귀인우전자적PO3-4-P화HMW Poly-P교후자유경대적염양강저량,이PO3-4-P, LMW Poly-P화HMW Poly-P교후자유경대적호양승고량,대응착중SRT(10 d)오니서체교고SRT(30 d)유경강적염양석린화호양흡린능력。
By adopting the activated sludge from two A/O-SBR reactors,of which the SRT are respectively 10 d and 30 d, effect of SRT on species and dynamic change of phosphates in sludge floc is investigated. The results show that phosphorus of sludge floc are mainly located in extracellular polymer substances (EPS) and the phosphorus contents of EPS are 69.45% to 73.36%of the total phosphorus contents of the sludge. Orthophosphate(PO3-4 -P)and polyphosphate(Poly-P)including low molec-ular weight polyphosphate(LMW Poly-P)and high molecular weight polyphosphate(HMW Poly-P)are the main species of sludge floc phosphorus. The phosphorus contents in high SRT(30 d)sludge EPS are much more than that in middle SRT(10 d)sludge EPS,which manifests that the former has more PO3-4 -P and HMW Poly-P contents than the latter,so the high SRT(30 d)sludge floc is related to the high phosphorus contents,and the phosphorus contents in the former are 1.37 times than those in the latter. Moreover,the decreased amount in anaerobic phase and increased amount in aerobic phase of middle SRT(10 d)sludge EPS phos- phorus are repectively 1.35 and 1.46 times than those of high SRT(30 d)sludge EPS phosphorus,which is mainly due to the fact that the PO3-4 -P and HMW Poly-P have more decreased amount in anaerobic phase and PO3-4 -P,LMW Poly-P and HMW Poly-P have more increased amount in aerobic phase of the former than those of the latter,so the middle SRT(10 d)sludge floc is related to the stronger anaerobic phosphorus release and aerobic phosphorus uptake capacities than the high SRT(30 d)sludge floc.