热带海洋学报
熱帶海洋學報
열대해양학보
JOURNAL OF TROPICAL OCEANOGRAPHY
2014年
3期
72-78
,共7页
姜双城%林培梅%林建伟%蔡建堤%许贻斌%郑乐云
薑雙城%林培梅%林建偉%蔡建隄%許貽斌%鄭樂雲
강쌍성%림배매%림건위%채건제%허이빈%정악운
厦门湾%沉积物%磷%赋存形态%环境意义
廈門灣%沉積物%燐%賦存形態%環境意義
하문만%침적물%린%부존형태%배경의의
Xiamen gulf%sediment%phosphorous%chemical speciation%environmental significance
2010年3月在厦门湾采集表层沉积物,应用改进的化学试剂连续分级浸取法(SEDEX)法对其中的弱吸附态磷(Ads-P)、铁结合态磷(Fe-P)、自生磷灰石及钙结合态磷(Ca-P)、碎屑态磷(De-P)和有机态磷(OP)的含量进行了分析测定,结合沉积物的环境参数,讨论了各种形态磷的地球化学行为。Ads-P、Fe-P、Ca-P、De-P、OP和总磷(TP)平均含量分别为9.80μg?g-1、148.69μg?g-1、14.07μg?g-1、136.89μg?g-1、91.97μg?g-1和401.41μg?g-1。研究表明,沉积物中的TP受陆源输入影响较小;Ads-P和Ca-P含量主要源于海区内部生物地球化学过程;De-P、OP和Fe-P主要受陆源输入影响;Ca-P、De-P和OP与重金属(Cu、Pb、Cd和As)具有化学耦合作用,在沉积过程中,可能具有相似地球化学行为。
2010年3月在廈門灣採集錶層沉積物,應用改進的化學試劑連續分級浸取法(SEDEX)法對其中的弱吸附態燐(Ads-P)、鐵結閤態燐(Fe-P)、自生燐灰石及鈣結閤態燐(Ca-P)、碎屑態燐(De-P)和有機態燐(OP)的含量進行瞭分析測定,結閤沉積物的環境參數,討論瞭各種形態燐的地毬化學行為。Ads-P、Fe-P、Ca-P、De-P、OP和總燐(TP)平均含量分彆為9.80μg?g-1、148.69μg?g-1、14.07μg?g-1、136.89μg?g-1、91.97μg?g-1和401.41μg?g-1。研究錶明,沉積物中的TP受陸源輸入影響較小;Ads-P和Ca-P含量主要源于海區內部生物地毬化學過程;De-P、OP和Fe-P主要受陸源輸入影響;Ca-P、De-P和OP與重金屬(Cu、Pb、Cd和As)具有化學耦閤作用,在沉積過程中,可能具有相似地毬化學行為。
2010년3월재하문만채집표층침적물,응용개진적화학시제련속분급침취법(SEDEX)법대기중적약흡부태린(Ads-P)、철결합태린(Fe-P)、자생린회석급개결합태린(Ca-P)、쇄설태린(De-P)화유궤태린(OP)적함량진행료분석측정,결합침적물적배경삼수,토론료각충형태린적지구화학행위。Ads-P、Fe-P、Ca-P、De-P、OP화총린(TP)평균함량분별위9.80μg?g-1、148.69μg?g-1、14.07μg?g-1、136.89μg?g-1、91.97μg?g-1화401.41μg?g-1。연구표명,침적물중적TP수륙원수입영향교소;Ads-P화Ca-P함량주요원우해구내부생물지구화학과정;De-P、OP화Fe-P주요수륙원수입영향;Ca-P、De-P화OP여중금속(Cu、Pb、Cd화As)구유화학우합작용,재침적과정중,가능구유상사지구화학행위。
Surface sediments were collected from the Xiamen Gulf in March 2010. The sediments were analyzed with modified SEDEX (sequential extraction and separation analysis method) to obtain Ads-P (absorbed phosphorus), Fe-P (iron-bound phosphorus), Ca-P (phosphate bound onto CaCO3), De-P (detritus phosphorus), and OP (organic phosphorus). Along with environmental parameters of sediments, the geochemistry characters of phosphorus were discussed.The mean contents of Ads-P, Fe-P, De-P, Ca-P, OP, and TP (total phosphorus) were 9.80, 48.69, 14.07, 136.89, 91.97, and 401.41μg?g-1, respectively. The results showed that TP was weakly influenced by terrestrial input, and De-P, OP and Fe-P were mainly influenced by terrestrial input. Ads-P and Ca-P were mainly from biogeochemical processes of the sea area. Ca-P, De-P and OP with heavy metals (Cu, Pb, Cd, and As) possessed chemical coupling, and might have similar geochemical behavior in the deposition process.