CAJ | 학술논문

以吡啶为溶剂，110℃加热6 h的反应条件下，芳香伯胺与丁二酸酐反应，主要生成N-芳香取代丁二酰亚胺，最高收率73.2％；相反，脂肪伯胺与丁二酸酐反应，主要产物为N-取代丁二酸单酰胺，收率72.5％～81.7％．探讨了结构-反应活性关系，并提出可能的反应机理．
이필정위용제，110℃가열6 h적반응조건하，방향백알여정이산항반응，주요생성N-방향취대정이선아알，최고수솔73.2％；상반，지방백알여정이산항반응，주요산물위N-취대정이산단선알，수솔72.5％～81.7％．탐토료결구-반응활성관계，병제출가능적반응궤리．
Byheatingat110℃for6happliedpyridineassolvent,themajorproductsofaromatic primary amines with succinic anhydride were N-substituted succinimides. The maximum yield was 73.2%;On the contrary,the main products of fatty primary amines with succinic anhydride were N-sub-stituted succinic acid mono-amides.The yields were arranged from 72.5%to 81.7%.The structure-re-activity relationship has been studied.A putative mechanism was also put forward.