CAJ | 학술논문

采用水-溶剂热法合成出钐配合物Sm （SSA ）（H2 O ）2· H2 O ，并通过元素分析、红外光谱、热重分析对其结构进行表征，利用紫外及荧光分光光度计研究配合物的光学性能，用X-射线单晶衍射仪测定配合物的晶体结构．结果表明，晶体属于单斜晶系，空间群为P2（1）/n；晶胞参数 a＝0.88844（16）nm ，b＝0.89254（16）nm ，c＝1.4366（3）nm ，α＝90.00°，β＝100.810（2）°，γ＝90.00°，Z＝4，V＝1.1190（3）nm3（CCDC No ．：875346）．中心金属离子Sm与周围的8个氧原子形成了四方反棱柱体的几何构型．
채용수-용제열법합성출삼배합물Sm （SSA ）（H2 O ）2· H2 O ，병통과원소분석、홍외광보、열중분석대기결구진행표정，이용자외급형광분광광도계연구배합물적광학성능，용X-사선단정연사의측정배합물적정체결구．결과표명，정체속우단사정계，공간군위P2（1）/n；정포삼수 a＝0.88844（16）nm ，b＝0.89254（16）nm ，c＝1.4366（3）nm ，α＝90.00°，β＝100.810（2）°，γ＝90.00°，Z＝4，V＝1.1190（3）nm3（CCDC No ．：875346）．중심금속리자Sm여주위적8개양원자형성료사방반릉주체적궤하구형．
A complex Sm(SSA)(H2O)2 · H2O has been synthesized from hydrothermal reaction and char-acterized by single crystal X-ray diffraction analysis ,studied by element analysis ,infrared spectrum and thermogravimetric analysis .The optical properties of the compound is studied by using UV-spectrum and fluorescent analysis .The result shows that the crystal structure belongs to Monoclinic ,space group P2 (1)/n with a=0.888 44(16)nm ,b=0.892 54(16)nm ,c=1.436 6(3)nm ,α=90.00° ,β=100.810(2)° ,γ=90.00° ,Z=4 ,V =1.1190(3)nm3 (CCDC No .:875346) .The samarium (Ⅲ ) ion is eight-coordinated by eight oxygen atoms formed a four party reverse prismoid geometric configuration .