CAJ | 학술논문

手性salen化合物是近几年发展起来的用于不对称催化反应的高效催化剂，自合成以来一直受到人们的关注。目前均相手性salen研究已相对成熟，但距离实现进一步的工业化还有很大差距。手性 salen化合物的固载化可望实现手性salen的工业化应用，已成为本领域的研究热点。从无机载体、有机载体和近几年发展起来的有机-无机复合载体3个方面综述了固载手性salen化合物的不同方法及研究进展，并做了分析比较。
수성salen화합물시근궤년발전기래적용우불대칭최화반응적고효최화제，자합성이래일직수도인문적관주。목전균상수성salen연구이상대성숙，단거리실현진일보적공업화환유흔대차거。수성 salen화합물적고재화가망실현수성salen적공업화응용，이성위본영역적연구열점。종무궤재체、유궤재체화근궤년발전기래적유궤-무궤복합재체3개방면종술료고재수성salen화합물적불동방법급연구진전，병주료분석비교。
Since chiral salen compounds were synthesized,they developed rapidly.Chiral salen compounds were widely used as catalysis for asymmetric reactions,but it was difficult to achieve industrial production.The im-mobilization of chiral salen compounds was found to be more effective to be applied to industrial production,and it attracted more and more attention.This review summarized different strategies and development to immobi-lize chiral salen compounds,going from organic supports,inorganic supports and new types of organic-inorganic hybrid material supports.The analysis and comparison of supported chiral salen compounds were also presented.