CAJ | 학술논문

以松木屑为原料，选取无水Na2CO3、无水Al2O3、凹凸棒土、ZSM-5共4类催化剂，利用管式炉实验及色质联用(GC-MS)分析仪进行热解特性研究，探索了热解产物产率和组分特性的变化规律．实验结果表明，松木屑在热解温度为550,℃时，产油率达到最大值51.47%(质量分数)；无催化剂条件下松木屑热解油主要成分为酸类化合物，加催化剂条件下松木屑热解油主要成分为酸类和酮类化合物，催化剂的加入主要影响了呋喃类、醇类、糖类和含氮类化合物的质量分数．ZSM-5催化剂的催化性能最佳，其能够提高热解油产率，其对应的热解油中酯类、呋喃类和芳香族类等能够提高热解油品质的化合物质量分数均较高，而糖类、含氮类等化合物质量分数较低，能够提高热解油的稳定性．
이송목설위원료，선취무수Na2CO3、무수Al2O3、요철봉토、ZSM-5공4류최화제，이용관식로실험급색질련용(GC-MS)분석의진행열해특성연구，탐색료열해산물산솔화조분특성적변화규률．실험결과표명，송목설재열해온도위550,℃시，산유솔체도최대치51.47%(질량분수)；무최화제조건하송목설열해유주요성분위산류화합물，가최화제조건하송목설열해유주요성분위산류화동류화합물，최화제적가입주요영향료부남류、순류、당류화함담류화합물적질량분수．ZSM-5최화제적최화성능최가，기능구제고열해유산솔，기대응적열해유중지류、부남류화방향족류등능구제고열해유품질적화합물질량분수균교고，이당류、함담류등화합물질량분수교저，능구제고열해유적은정성．
Pine sawdust as material,Na2CO3,anhydrous Al2O3,attapulgite and ZSM-5 as catalysts, pyrolysis characteristics are studied using a tubular furnace reactor and the gas chromatography-mass spectrometry(GC-MS). The yield and composition of pyrolysis products are also investigated. The experimental results show that the maximal oil yield of pine sawdust is about 51.47%(mass fraction)when the pyrolysis temperature is 550,℃. In the absence of catalyst,the main ingredients of pine sawdust pyrolysis oil are acid compounds,while the main ingredients are acids and ketone compounds in the presence of catalyst. Catalysts mainly affect the mass fraction of furan,alcohol, saccharides and nitrogen compounds. ZSM-5,shows the best catalytic performance,which can improve the pyrolysis oil yield. There are higher mass fraction of esters,furan and aromatic species in its corresponding pyrolysis oil, which can improve the pyrolysis oil quality,while the mass fraction of carbohydrates and nitrogen compounds are lower,which can improve the stability of pyrolysis oil.