淮阴师范学院学报(自然科学版)
淮陰師範學院學報(自然科學版)
회음사범학원학보(자연과학판)
JOURNAL OF HUAIYIN TEACHERS COLLEGE (NATURAL SCIENCE EDITION)
2014年
3期
214-217
,共4页
杨凡%褚效中%张春艳%朱永梅%杨青%张盈
楊凡%褚效中%張春豔%硃永梅%楊青%張盈
양범%저효중%장춘염%주영매%양청%장영
凹凸棒黏土%硫酸氢钠%固体酸催化剂
凹凸棒黏土%硫痠氫鈉%固體痠催化劑
요철봉점토%류산경납%고체산최화제
attapulgite%sodium bisulfate%solid acid catalyst
硫酸氢钠是一种重要的无机盐化工原料及无机盐固体酸催化剂,但在实际使用中存在诸多缺陷.以廉价凹凸棒黏土(凹土)为载体开发高附加值的固体酸催化剂,研究了提高凹土比表面积与成型的方法;分别运用浸渍法和热分散法制备了复合固体酸催化剂,并考察了这两类催化剂对环己醇脱水反应的催化性能.结果表明,凹土比表面积可达233.7 m2/g,环己醇脱水时间由54 min缩短到30 min.
硫痠氫鈉是一種重要的無機鹽化工原料及無機鹽固體痠催化劑,但在實際使用中存在諸多缺陷.以廉價凹凸棒黏土(凹土)為載體開髮高附加值的固體痠催化劑,研究瞭提高凹土比錶麵積與成型的方法;分彆運用浸漬法和熱分散法製備瞭複閤固體痠催化劑,併攷察瞭這兩類催化劑對環己醇脫水反應的催化性能.結果錶明,凹土比錶麵積可達233.7 m2/g,環己醇脫水時間由54 min縮短到30 min.
류산경납시일충중요적무궤염화공원료급무궤염고체산최화제,단재실제사용중존재제다결함.이렴개요철봉점토(요토)위재체개발고부가치적고체산최화제,연구료제고요토비표면적여성형적방법;분별운용침지법화열분산법제비료복합고체산최화제,병고찰료저량류최화제대배기순탈수반응적최화성능.결과표명,요토비표면적가체233.7 m2/g,배기순탈수시간유54 min축단도30 min.
Sodium bisulfate is a kind of important inorganic raw materials in chemical engineering and inor-ganic solid acid catalyst.However, there are some defects in the practical use.A high value-added solid acid catalyst was developed with cheap attapulgite as a carrier.The method of enhancing specific surface area of at-tapulgite and molding method were studied.Complex solid acid catalyst was prepared using the impregnation method and heat dispersion method, respectively.Moreover, catalytic activity on cyclohexanol dehydration reac-tion was investigated with these two types of catalysts .The results show that the specific surface area of attapulg-ite is up to 233.7 m2/g, and the time of cyclohexanol dehydration reaction is shortened from 54 min to 30 min.