浙江理工大学学报
浙江理工大學學報
절강리공대학학보
JOURNAL OF ZHEJIANG SCI-TECH UNIVERSITY
2014年
2期
133-137
,共5页
秦永瑞%楼添良%陈雪菲%张明毓%胡国樑
秦永瑞%樓添良%陳雪菲%張明毓%鬍國樑
진영서%루첨량%진설비%장명육%호국량
PP分离膜%酸处理%结构%性能
PP分離膜%痠處理%結構%性能
PP분리막%산처리%결구%성능
PP separation membrane%acid treatment%structure%property
对聚丙烯分离膜进行盐酸腐蚀处理后,得到不同处理浓度下分离膜各项性能的变化规律。通过对分离膜的形态结构、浸润性能和物理机械性能进行研究,结果表明:经过盐酸处理1d后,膜表面的浸润性均消失;在0.015 mol/L和0.025 mol/L的盐酸处理3 d后,分离膜导水率的保持率分别为50.33%和3.01%,此时膜的厚度均达到了最大值,较原样分别增加了14.75%和19.30%;在0.005、0.015 mol/L和0.025 mol/L的盐酸处理7 d后,断裂强度分别下降了5%、8.54%和12.19%,平均孔径分别下降了7.68%、11.98%和21.88%;而膜的接触角和透气率对盐酸浓度的变化不敏感。
對聚丙烯分離膜進行鹽痠腐蝕處理後,得到不同處理濃度下分離膜各項性能的變化規律。通過對分離膜的形態結構、浸潤性能和物理機械性能進行研究,結果錶明:經過鹽痠處理1d後,膜錶麵的浸潤性均消失;在0.015 mol/L和0.025 mol/L的鹽痠處理3 d後,分離膜導水率的保持率分彆為50.33%和3.01%,此時膜的厚度均達到瞭最大值,較原樣分彆增加瞭14.75%和19.30%;在0.005、0.015 mol/L和0.025 mol/L的鹽痠處理7 d後,斷裂彊度分彆下降瞭5%、8.54%和12.19%,平均孔徑分彆下降瞭7.68%、11.98%和21.88%;而膜的接觸角和透氣率對鹽痠濃度的變化不敏感。
대취병희분리막진행염산부식처리후,득도불동처리농도하분리막각항성능적변화규률。통과대분리막적형태결구、침윤성능화물리궤계성능진행연구,결과표명:경과염산처리1d후,막표면적침윤성균소실;재0.015 mol/L화0.025 mol/L적염산처리3 d후,분리막도수솔적보지솔분별위50.33%화3.01%,차시막적후도균체도료최대치,교원양분별증가료14.75%화19.30%;재0.005、0.015 mol/L화0.025 mol/L적염산처리7 d후,단렬강도분별하강료5%、8.54%화12.19%,평균공경분별하강료7.68%、11.98%화21.88%;이막적접촉각화투기솔대염산농도적변화불민감。
After hydrochloric acid corrosion of PP separation membrane ,the change laws of various properties of the separation membrane at different treatment concentrations are gained .The results show that the wettability of the membrane surface disappeared after it is treated by hydrochloric acid for 1 day ;the retention rates of the membrane's hydraulic conductivity are 50 .33% and 3 .01% respectively after it is treated for 3 days by 0 .015 mol/L and 0 .025 mol/L hydrochloric acid ;and at this point ,the membrane thickness reached the maximum value and respectively increases by 14 .75% and 19 .30% ;the breaking strength respectively declined by 5% ,8 .54% and 12 .19% and the average pore diameter respectively de-clined by 7 .68% ,11 .98% and 21 .88% ,after it is treated for 7 days by the hydrochloric acid at 0 .005 mol/L ,0 .015 mol/L and 0 .025 mol/L ;the contact angle and permeability of the membrane are insensitive to variations in the concentration of hydrochloric acid .