CAJ | 학술논문

利用均相反应器,在没有添加剂的条件下合成了具有多孔结构的Cu2O微球.考察了合成时间以及反应器旋转速度对Cu2O微球结构的影响.通过增加聚乙烯吡咯烷酮(PVP)的用量,使得Cu2O从多孔微球转变为立方体孪晶,最终形成十四面体孪晶结构.同时,将不同结构的Cu2O多晶应用于催化高氯酸铵(AP)的热分解,结果表明：多孔Cu2O微球较其它结构的Cu2O对AP的热分解具有更高的催化活性,使得AP的低温分解温度降低了37.4°C,而AP在低温阶段的分解量也由8.7%增加至49.0%.
이용균상반응기,재몰유첨가제적조건하합성료구유다공결구적Cu2O미구.고찰료합성시간이급반응기선전속도대Cu2O미구결구적영향.통과증가취을희필각완동(PVP)적용량,사득Cu2O종다공미구전변위립방체련정,최종형성십사면체련정결구.동시,장불동결구적Cu2O다정응용우최화고록산안(AP)적열분해,결과표명：다공Cu2O미구교기타결구적Cu2O대AP적열분해구유경고적최화활성,사득AP적저온분해온도강저료37.4°C,이AP재저온계단적분해량야유8.7%증가지49.0%.
Porous Cu2O micro-spheres were synthesized without additives, using a homogeneous reactor. The effects of synthesis time and reactor rol ing speed on the Cu2O micro-spheres structure were investigated. Increasing the use of polyvinylpyrrolidone, the porous Cu2O micro-spheres transformed into cubic twined crystals, and then into cubic-octahedral twined crystals. Cu2O micro-crystals with different structures were used to catalyze the thermal decomposition of ammonium perchlorate (AP). The catalytic activity of porous Cu2O micro-spheres was better than those of the cubic twined and cubic-octahedral twined crystals. The low temperature of AP decomposition decreased for 37.4 °C when catalyzed by the porous Cu2O micro-spheres, and amount of AP decomposed at low temperature increased from 8.7%to 49.0%.