化学研究与应用
化學研究與應用
화학연구여응용
CHEMICAL RESEARCH AND APPLICATION
2014年
2期
175-179
,共5页
三元杂多酸盐%聚苯胺%亚甲基蓝%光催化降解
三元雜多痠鹽%聚苯胺%亞甲基藍%光催化降解
삼원잡다산염%취분알%아갑기람%광최화강해
ternary heteropoly acid%polyaniline%methylene blue%photocatalytic degration
采用化学氧化法制得K8[CuW11 CdO40]/PANI掺杂材料,并用IR、UV、XRD、EDS、SEM对所合成的掺杂材料进行了表征。并利用所合成K 8[CuW 11CdO 40]/PANI掺杂材料为催化剂,研究了对亚甲基蓝溶液光降解催化活性。通过实验确定了光降解的最佳条件为:亚甲基蓝溶液初始pH为2,亚甲基蓝溶液初始浓度为10 mg?L-1,催化剂用量为0.08 g,在光照100 min,亚甲基蓝溶液的脱色率为98.11%。因此,K8[CuW11 CdO40]/PANI掺杂材料是一种很好的光降解催化剂。
採用化學氧化法製得K8[CuW11 CdO40]/PANI摻雜材料,併用IR、UV、XRD、EDS、SEM對所閤成的摻雜材料進行瞭錶徵。併利用所閤成K 8[CuW 11CdO 40]/PANI摻雜材料為催化劑,研究瞭對亞甲基藍溶液光降解催化活性。通過實驗確定瞭光降解的最佳條件為:亞甲基藍溶液初始pH為2,亞甲基藍溶液初始濃度為10 mg?L-1,催化劑用量為0.08 g,在光照100 min,亞甲基藍溶液的脫色率為98.11%。因此,K8[CuW11 CdO40]/PANI摻雜材料是一種很好的光降解催化劑。
채용화학양화법제득K8[CuW11 CdO40]/PANI참잡재료,병용IR、UV、XRD、EDS、SEM대소합성적참잡재료진행료표정。병이용소합성K 8[CuW 11CdO 40]/PANI참잡재료위최화제,연구료대아갑기람용액광강해최화활성。통과실험학정료광강해적최가조건위:아갑기람용액초시pH위2,아갑기람용액초시농도위10 mg?L-1,최화제용량위0.08 g,재광조100 min,아갑기람용액적탈색솔위98.11%。인차,K8[CuW11 CdO40]/PANI참잡재료시일충흔호적광강해최화제。
The doping materials of K 8 [CuW11 CdO40 ]/PANI were prepared by the chemical oxidation method ,and were character-ized by UV、IR、XRD、SEM、EDM.The photocatalytic degration acitity of methylene blue solution was studied by doping materials catalyst.The experment results indicated that the most suitable conditions of photocatalytic degradation were that the initial pH of methylene blue solution was 2,the initial concentration of methylene blue solution was 10 mg?L-1,the catalyst quantity were 0.08g, within 110 min the decolorizing efficiency of the methylene blue solution was 98.11%.so K 8[CuW 11CdO 40]/PANI was the good photocatalytic degration catalyst.