光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
2期
548-552
,共5页
陈辉%王志斌%常巧英%王伟%范春林%庞国芳
陳輝%王誌斌%常巧英%王偉%範春林%龐國芳
진휘%왕지빈%상교영%왕위%범춘림%방국방
油菜蜜%油菜花%油菜杆%IC P-M S%微量元素%雷达图谱
油菜蜜%油菜花%油菜桿%IC P-M S%微量元素%雷達圖譜
유채밀%유채화%유채간%IC P-M S%미량원소%뢰체도보
Rape honey%Rape flower%Rape stem%ICP-MS%Trace element%Radar map
应用电感耦合等离子体质谱(IC P-M S )测定了收集于9个采样点的油菜蜜及其蜜源油菜花和油菜杆中Na ,Mg ,P ,K ,Ca ,Mn ,Zn ,Rb ,Sr和Ba等10种元素。在油菜蜜、油菜花和油菜杆中K ,P ,Ca ,Mg和Na等五种元素含量均明显高于Zn ,Rb ,Mn ,Sr和Ba ,前五种元素含量大小顺序为K> P>Ca> Mg> Na ,后五种元素含量在三者中的大小顺序则不尽相同。油菜花和油菜杆中K ,P和Ca三种元素的含量均高于1000 mg · kg -1,油菜花中P ,Ca ,M n ,Zn和Rb等五种元素的平均含量均高于油菜杆,可以初步推断油菜花富集元素的能力略强于油菜杆。在上述测定结果基础上,首次应用雷达图对油菜蜜及其蜜源油菜花和油菜杆中10种元素的关系进行了研究,主要是为了对将油菜花中元素含量用于蜂蜜溯源研究的可能性进行探索。从雷达图可以看出,10种元素在油菜蜜、油菜花和油菜杆中的星形基本类似。此研究为油菜蜜的相关研究提供基础数据,同时为利用油菜花中元素含量代替油菜蜜中元素含量进行油菜蜜溯源提供了一定的科学依据。
應用電感耦閤等離子體質譜(IC P-M S )測定瞭收集于9箇採樣點的油菜蜜及其蜜源油菜花和油菜桿中Na ,Mg ,P ,K ,Ca ,Mn ,Zn ,Rb ,Sr和Ba等10種元素。在油菜蜜、油菜花和油菜桿中K ,P ,Ca ,Mg和Na等五種元素含量均明顯高于Zn ,Rb ,Mn ,Sr和Ba ,前五種元素含量大小順序為K> P>Ca> Mg> Na ,後五種元素含量在三者中的大小順序則不儘相同。油菜花和油菜桿中K ,P和Ca三種元素的含量均高于1000 mg · kg -1,油菜花中P ,Ca ,M n ,Zn和Rb等五種元素的平均含量均高于油菜桿,可以初步推斷油菜花富集元素的能力略彊于油菜桿。在上述測定結果基礎上,首次應用雷達圖對油菜蜜及其蜜源油菜花和油菜桿中10種元素的關繫進行瞭研究,主要是為瞭對將油菜花中元素含量用于蜂蜜溯源研究的可能性進行探索。從雷達圖可以看齣,10種元素在油菜蜜、油菜花和油菜桿中的星形基本類似。此研究為油菜蜜的相關研究提供基礎數據,同時為利用油菜花中元素含量代替油菜蜜中元素含量進行油菜蜜溯源提供瞭一定的科學依據。
응용전감우합등리자체질보(IC P-M S )측정료수집우9개채양점적유채밀급기밀원유채화화유채간중Na ,Mg ,P ,K ,Ca ,Mn ,Zn ,Rb ,Sr화Ba등10충원소。재유채밀、유채화화유채간중K ,P ,Ca ,Mg화Na등오충원소함량균명현고우Zn ,Rb ,Mn ,Sr화Ba ,전오충원소함량대소순서위K> P>Ca> Mg> Na ,후오충원소함량재삼자중적대소순서칙불진상동。유채화화유채간중K ,P화Ca삼충원소적함량균고우1000 mg · kg -1,유채화중P ,Ca ,M n ,Zn화Rb등오충원소적평균함량균고우유채간,가이초보추단유채화부집원소적능력략강우유채간。재상술측정결과기출상,수차응용뢰체도대유채밀급기밀원유채화화유채간중10충원소적관계진행료연구,주요시위료대장유채화중원소함량용우봉밀소원연구적가능성진행탐색。종뢰체도가이간출,10충원소재유채밀、유채화화유채간중적성형기본유사。차연구위유채밀적상관연구제공기출수거,동시위이용유채화중원소함량대체유채밀중원소함량진행유채밀소원제공료일정적과학의거。
The determination of 10 trace elements including Na ,Mg ,P ,K ,Ca ,Mn ,Zn ,Rb ,Sr and Ba ,in rape honey and its corresponding rape flower and stem gathered from nine sampling sites was carried out by in-ductively coupled plasma mass spectrometry (ICP-MS) .The contents of K ,P ,Ca ,Mg and Na were obviously higher than Zn ,Rb ,Mn ,Sr and Ba in rape honey ,rape flower and rape stem .For the first five elements ,K had the highest content ,followed by P ,Ca ,Mg and Na .However ,the order of content for latter five ele-ments was not the same in different matrixes .The contents of K ,P and Ca were all higher than 1 000 mg · kg -1 in rape flower and rape stem ,while the contents of P ,Ca ,Mn ,Zn and Rb in rape flower were slightly higher than in rape stem .It can be concluded that rape flower showed slightly higher concentrating ability for trace elements than rape stem .Based on these results ,radar chart was firstly applied to research the relation-ship of 10 elements in rape honey and its corresponding rape flower and stem .The aim of the present work was to study the possibility of using trace elements contents in rape flower to trace the geographical and botanical origin of honey instead of rape honey .It can be found from the radar charts that the stars of rape honey ,rape flower and rape stem were similar to each other .This research not only provides the basic data of trace ele-ments in comparative study of rape honey ,but also gives scientific basis for tracing the origin of rape honey ac-cording to the trace elements in corresponding rape flower that replaces those of rape honey .