光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
2期
450-454
,共5页
汤景梅%梁淑轩%孙汉文%刘山%王丽华
湯景梅%樑淑軒%孫漢文%劉山%王麗華
탕경매%량숙헌%손한문%류산%왕려화
府河%溶解性有机质%三维荧光光谱%相关性
府河%溶解性有機質%三維熒光光譜%相關性
부하%용해성유궤질%삼유형광광보%상관성
Fu River%Dissolved organic matter%Excitation-emission matrix fluorescence spectroscopy%Corre-lation
利用三维荧光光谱法(3D-EEM )研究了保定府河溶解性有机质(DOM )的荧光特性,根据三维荧光光谱图中荧光峰的位置、数量及强度变化,荧光峰之间的相关性,初步判断荧光物质的类别、分布和来源。府河水体溶解性有机质主要有类蛋白质和类溶解性微生物代谢产物两类,类蛋白荧光峰 Ex/Em=225~230/340 nm(A);类溶解性微生物代谢产物荧光峰Ex/Em=275/340~350 nm(B)。不同采样时间和采样点,府河水体基本上都存在类蛋白荧光峰和类溶解性微生物代谢产物荧光峰。分析各荧光峰强度与水质指标相关性发现,两荧光峰之间呈显著性相关,表明研究区域中类蛋白质和类溶解性微生物代谢产物具有同源性;DOM两类荧光峰与COD ,T N ,T P ,N H3-N呈显著正相关,表明通过两类荧光峰强度可推测府河污染程度,为府河污染防治和沿河流域生态环境治理提供参考。
利用三維熒光光譜法(3D-EEM )研究瞭保定府河溶解性有機質(DOM )的熒光特性,根據三維熒光光譜圖中熒光峰的位置、數量及彊度變化,熒光峰之間的相關性,初步判斷熒光物質的類彆、分佈和來源。府河水體溶解性有機質主要有類蛋白質和類溶解性微生物代謝產物兩類,類蛋白熒光峰 Ex/Em=225~230/340 nm(A);類溶解性微生物代謝產物熒光峰Ex/Em=275/340~350 nm(B)。不同採樣時間和採樣點,府河水體基本上都存在類蛋白熒光峰和類溶解性微生物代謝產物熒光峰。分析各熒光峰彊度與水質指標相關性髮現,兩熒光峰之間呈顯著性相關,錶明研究區域中類蛋白質和類溶解性微生物代謝產物具有同源性;DOM兩類熒光峰與COD ,T N ,T P ,N H3-N呈顯著正相關,錶明通過兩類熒光峰彊度可推測府河汙染程度,為府河汙染防治和沿河流域生態環境治理提供參攷。
이용삼유형광광보법(3D-EEM )연구료보정부하용해성유궤질(DOM )적형광특성,근거삼유형광광보도중형광봉적위치、수량급강도변화,형광봉지간적상관성,초보판단형광물질적유별、분포화래원。부하수체용해성유궤질주요유류단백질화류용해성미생물대사산물량류,류단백형광봉 Ex/Em=225~230/340 nm(A);류용해성미생물대사산물형광봉Ex/Em=275/340~350 nm(B)。불동채양시간화채양점,부하수체기본상도존재류단백형광봉화류용해성미생물대사산물형광봉。분석각형광봉강도여수질지표상관성발현,량형광봉지간정현저성상관,표명연구구역중류단백질화류용해성미생물대사산물구유동원성;DOM량류형광봉여COD ,T N ,T P ,N H3-N정현저정상관,표명통과량류형광봉강도가추측부하오염정도,위부하오염방치화연하류역생태배경치리제공삼고。
The fluorescence properties of dissolved organic matter (DOM ) in Fu River in Baoding were investi-gated by three-dimensional fluorescence spectrometry .The type ,distribution and origin of the DOM were esti-mated on basis of the position ,number and intensity of fluorescence peaks in the spectra .Two types of fluo-rescence peaks were detected from Fu River .There are protein-like fluorescence peaks A with Ex/Em=225~230/340 nm and soluble microbial metabolites peaks B with Ex/Em=275/340~350 nm .The protein-like fluo-rescence peaks and soluble microbial metabolites peaks were founded in different times and stations in Fu Riv-er .Certain correlation was observed between the fluorescence intensity of DOM and the water quality parame-ters of Fu River .Good correlation of different fluorescence peaks showed the same of source .The fluorescence intensity of the two types had a significant positive relationship with COD ,TN ,TP and NH3-N concentration , this phenomenon indicating that the fluorescence peaks can speculate the level of pollution of Fu River .These results provided a reference for the pollution control in Fu River .