CAJ | 학술논문

以市售立邦水性涂料作为研究对象，溶剂水作为变量因子。配制不同水料比的涂料系列样品，分别用FTIR/ATR、FTIR/漫反射光谱表征湿料、涂膜的微观结构特征，湿料抽滤得到的固型物用FTIR/漫反射光谱表征。分析其官能团变化情况，研究施工过程，溶剂对涂膜的影响。结果显示：随着加水量的增加，湿料的FTIR/ATR光谱中，1727 cm -1对应的羰基吸收峰，逐渐转为肩峰，871 cm -1吸收峰发生蓝移，峰强度逐渐减弱；涂膜的漫反射红外图谱，3400 cm-1的-O H吸收峰、3030 cm-1不饱和-C H吸收峰强度逐渐变弱，2962和2871 cm -1的甲基和亚甲基的吸收峰强度逐渐增强，2516 cm-1吸收峰位移至2603 cm-1形成肩峰，1647 cm-1吸收峰逐渐位移至1455 cm -1，1107 cm -1对应的C-O伸缩振动吸收峰发生红移。在水性涂料施工过程中，溶剂水与涂料分子间存在相互作用，对涂层分子中电子云的密度分布有显著的影响，此结果对涂料的生产及施工有参考意义。
이시수립방수성도료작위연구대상，용제수작위변량인자。배제불동수료비적도료계렬양품，분별용FTIR/ATR、FTIR/만반사광보표정습료、도막적미관결구특정，습료추려득도적고형물용FTIR/만반사광보표정。분석기관능단변화정황，연구시공과정，용제대도막적영향。결과현시：수착가수량적증가，습료적FTIR/ATR광보중，1727 cm -1대응적탄기흡수봉，축점전위견봉，871 cm -1흡수봉발생람이，봉강도축점감약；도막적만반사홍외도보，3400 cm-1적-O H흡수봉、3030 cm-1불포화-C H흡수봉강도축점변약，2962화2871 cm -1적갑기화아갑기적흡수봉강도축점증강，2516 cm-1흡수봉위이지2603 cm-1형성견봉，1647 cm-1흡수봉축점위이지1455 cm -1，1107 cm -1대응적C-O신축진동흡수봉발생홍이。재수성도료시공과정중，용제수여도료분자간존재상호작용，대도층분자중전자운적밀도분포유현저적영향，차결과대도료적생산급시공유삼고의의。
borne paint was studied in the article in which the solvent water was regarded as a variable factor .A series of paint samples with different percentage of water were configured before observing their storage performance and microstructures by u-sing Fourier-transform infrared (FTIR) ATR (attenuated total reflection ) spectroscopy and diffuse reflectance (DF) FTIR spec-troscopy .The effects of construction process and solvent water on the coating film were examined through analyzing the changes of internal functional groups before and after coating .The results indicated that as the amount of solvent water was increased , the characteristic peak of νC in 1 727 cm -1 turned into acromion ,the absorption peak in 871 cm-1 was blue shifted ,the inten-sity of the peak of hydroxyl (νOH ) in 3 400 cm-1 and unsaturated absorption peak of ν-CH in 3 030 cm-1 gradually weakened ,the absorption peaks strengths of ν-CH3 and ν-CH2 in 2 962 and 2 871 cm-1 increased ,respectively .The absorption peak in 2 516 cm -1 was shifted to 2 603 cm -1 then form the acromion ,the absorption peak of 1 647 cm-1 gradually changed to 1 455 cm-1 ,the stretching vibration absorption peak of νC- O in 1 107 cm -1 was red-shifted .During the coating process of paint ,the solvent water and paint molecules interacted with each other ,having a significant impact on the electron cloud density distribution of the paint molecules .The results obtained in the article have an important significance for the production and construction of paint .