CAJ | 학술논문

采用程序升温脱附方法研究了甲醇分子吸附在真空退火后的二氧化钛(110)表面的光催化过程，对比分析了单独吸附甲醇分子以及甲醇分子与水分子共吸附情况下的光催化解离过程。结果表明，在二氧化钛(110)表面吸附的甲醇分子对共吸附水分子的光催化解离过程并没有直接的帮助作用。共吸附状态下的水分子也同样没有影响到甲醇的光致解离过程，但是水分子的存在抑制了甲醇光解产物甲醛的光致脱附过程，同时促进了甲酸甲酯的形成。
채용정서승온탈부방법연구료갑순분자흡부재진공퇴화후적이양화태(110)표면적광최화과정，대비분석료단독흡부갑순분자이급갑순분자여수분자공흡부정황하적광최화해리과정。결과표명，재이양화태(110)표면흡부적갑순분자대공흡부수분자적광최화해리과정병몰유직접적방조작용。공흡부상태하적수분자야동양몰유영향도갑순적광치해리과정，단시수분자적존재억제료갑순광해산물갑철적광치탈부과정，동시촉진료갑산갑지적형성。
We have performed a surface photocatalysis study of the molecularly adsorbed forms of methanol on a vacuum-annealed rutile TiO2(110)-(1 × 1) surface using temperature-programmed desorption both with and without coadsorbed water to investigate the effect of water and methanol on the photocatalytic dissociation of each other on rutile TiO2(110)-(1 × 1). Our experimental results show conclusively that methanol has no effect on photocatalytic water splitting with water covered rutile TiO2(110)-(1 × 1) surface. Further experimental results also show that water does not affect the process of photocatalytic methanol dissociation but does suppress photo-induced desorption of the formaldehyde product of methanol photocatalysis and can enhance the formation of the methyl formate product.