广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2014年
18期
66-67,70
,共3页
赵敏敏%吴周强%苏成武%沈彤
趙敏敏%吳週彊%囌成武%瀋彤
조민민%오주강%소성무%침동
孔雀石绿%缔合平衡常数%SDS
孔雀石綠%締閤平衡常數%SDS
공작석록%체합평형상수%SDS
malachite green%association constant%SDS
通过测量孔雀石绿在十二烷基硫酸钠水溶液紫外吸收光谱，我们发现在孔雀石绿与SDS之间存在着一种相互缔合的作用。通过建立适当热力学模型，测量孔雀石绿在一系列SDS水溶液中的吸光度，得到了孔雀石绿与SDS在水溶液缔合平衡常数K和热力学参数Δr Gm。
通過測量孔雀石綠在十二烷基硫痠鈉水溶液紫外吸收光譜，我們髮現在孔雀石綠與SDS之間存在著一種相互締閤的作用。通過建立適噹熱力學模型，測量孔雀石綠在一繫列SDS水溶液中的吸光度，得到瞭孔雀石綠與SDS在水溶液締閤平衡常數K和熱力學參數Δr Gm。
통과측량공작석록재십이완기류산납수용액자외흡수광보，아문발현재공작석록여SDS지간존재착일충상호체합적작용。통과건립괄당열역학모형，측량공작석록재일계렬SDS수용액중적흡광도，득도료공작석록여SDS재수용액체합평형상수K화열역학삼수Δr Gm。
The absorption spectrum of malachite green ( MG) in series of aqueous solutions with surfactant SDS was determined by the UV -Vis spectrophotometer.There was association interaction existed between the MG with cationic surfactant SDS in aqueous solutions , which resulted in obvious fading of MG.The thermodynamics model of association between MG with SDS was established , and the association equilibrium constant and thermodynamic parameters Δr Gm in aqueous solution was determined.
