湿法冶金
濕法冶金
습법야금
HYDROMETALLURGY OF CHINA
2013年
6期
371-375
,共5页
戴曦%陈田庄%吴永谦%周康洁%李良斌
戴晞%陳田莊%吳永謙%週康潔%李良斌
대희%진전장%오영겸%주강길%리량빈
锌焙砂%闪速还原焙烧%选择性浸出%锌%铁
鋅焙砂%閃速還原焙燒%選擇性浸齣%鋅%鐵
자배사%섬속환원배소%선택성침출%자%철
zinc calcine%flash reduction roasting%selective leaching%zinc%iron
研究了从锌焙砂闪速还原焙烧产物中选择性酸浸锌,考察了初始硫酸质量浓度、浸出温度、浸出时间、液固体积质量比、搅拌速度对锌、铁浸出率的影响。试验结果表明:还原锌焙砂的锌浸出率较锌焙砂的锌浸出率提高10%以上,其浸出渣中含铁质量分数提高7%以上;还原锌焙砂结构疏松多孔,使其及浸出渣的过滤性能得以改善。高效分解锌焙砂中ZnFe2 O4并形成理想形态的磁性化合物Fe3 O4,是提高还原锌焙砂锌浸出率并抑制铁浸出从而实现锌、铁有效分离的关键。
研究瞭從鋅焙砂閃速還原焙燒產物中選擇性痠浸鋅,攷察瞭初始硫痠質量濃度、浸齣溫度、浸齣時間、液固體積質量比、攪拌速度對鋅、鐵浸齣率的影響。試驗結果錶明:還原鋅焙砂的鋅浸齣率較鋅焙砂的鋅浸齣率提高10%以上,其浸齣渣中含鐵質量分數提高7%以上;還原鋅焙砂結構疏鬆多孔,使其及浸齣渣的過濾性能得以改善。高效分解鋅焙砂中ZnFe2 O4併形成理想形態的磁性化閤物Fe3 O4,是提高還原鋅焙砂鋅浸齣率併抑製鐵浸齣從而實現鋅、鐵有效分離的關鍵。
연구료종자배사섬속환원배소산물중선택성산침자,고찰료초시류산질량농도、침출온도、침출시간、액고체적질량비、교반속도대자、철침출솔적영향。시험결과표명:환원자배사적자침출솔교자배사적자침출솔제고10%이상,기침출사중함철질량분수제고7%이상;환원자배사결구소송다공,사기급침출사적과려성능득이개선。고효분해자배사중ZnFe2 O4병형성이상형태적자성화합물Fe3 O4,시제고환원자배사자침출솔병억제철침출종이실현자、철유효분리적관건。
Selective acid leaching of zinc and iron from flash reduction roasting product was studied .The influence of initial sulfuric acid concentration ,leaching temperature ,leaching time ,the ratio between liquid volume and solid mass ,stirring rate on leaching of zinc and iron were studied .The results show that the leaching rate of zinc increases more than 10% after zinc calcine being reduction roasted ,iron content in the leaching residue increases more than 7% .The leaching as well as filtering performance are improved due to the porous structure of reduction zinc calcine .The formation of the desired magnetic compound Fe3 O4 by efficient decomposition of ZnFe2 O4 in zinc calcine is effective to separate zinc and iron .