CAJ | 학술논문

为研究高能化合物 FOX-7在发射药中的应用，采用溶剂法制备3种 FOX-7含量不同的发射药样品，利用DSC对发射药进行分析，以及密闭爆发器试验，并针对FOX7-3发射药还进行高低常温试验比较。试验结果表明：发射药的热分解与配方中 FOX7含量成正比关系，热分解温度随 FOX-7含量增加而增高；配方中含 FOX-7较高的发射药(FOX7-3)，能量较高(火药力为1030.42 J/g)，燃速较快(燃速系数为0.0516，压力指数为1.066)，且燃烧渐增性较好；FOX7-3发射药在高、低、常温下燃烧性能稳定，低温没有出现碎裂的现象。FOX-7在发射药中能够显著提高发射药的火药力，温度系数较稳定，在一定的范围内，通过调整FOX-7的含量能够获得火药力较高和燃烧渐增性较好的发射药。
위연구고능화합물 FOX-7재발사약중적응용，채용용제법제비3충 FOX-7함량불동적발사약양품，이용DSC대발사약진행분석，이급밀폐폭발기시험，병침대FOX7-3발사약환진행고저상온시험비교。시험결과표명：발사약적열분해여배방중 FOX7함량성정비관계，열분해온도수 FOX-7함량증가이증고；배방중함 FOX-7교고적발사약(FOX7-3)，능량교고(화약력위1030.42 J/g)，연속교쾌(연속계수위0.0516，압력지수위1.066)，차연소점증성교호；FOX7-3발사약재고、저、상온하연소성능은정，저온몰유출현쇄렬적현상。FOX-7재발사약중능구현저제고발사약적화약력，온도계수교은정，재일정적범위내，통과조정FOX-7적함량능구획득화약력교고화연소점증성교호적발사약。
Three gun propellant samples with different content of FOX-7 were prepared by solvent method to investigate the application of FOX-7 in gun propellant. The thermal behavior and combustion property of the propellants containing FOX-7 were studied by DSC and closed bomb test. The closed bomb test of propellant sample FOX7-3 was carried out at high, low, normal temperature respectively. The results show that thermal decomposition temperature of gun propellants containing FOX-7 is proportional to the content of FOX-7. The energy of sample FOX7-3 (with higher content of FOX-7) is higher than others. The burning rate of sample FOX7-3 is faster and burning progressivity is better than others. The burning behavior of sample FOX7-3 under high, low and normal temperature is stable. There is no disintegration phenomenon at low temperature. The specific energy of gun propellant can be increased by adding FOX-7. The temperature coefficient is also stable. By changing the content of FOX-7 in gun propellant, the specific energy of gun propellant can be increased and the burning progressivity can be improved.