陕西科技大学学报(自然科学版)
陝西科技大學學報(自然科學版)
협서과기대학학보(자연과학판)
JOURNAL OF SHAANXI UNIVERSITY OF SCIENCE & TECHNOLOGY
2013年
6期
73-76,94
,共5页
郝航飞%谈国强%耶维%晏霞%任慧君
郝航飛%談國彊%耶維%晏霞%任慧君
학항비%담국강%야유%안하%임혜군
K0 .5 Na0 .5 NbO3%BiFeO3%水热法%无铅压电%掺杂
K0 .5 Na0 .5 NbO3%BiFeO3%水熱法%無鉛壓電%摻雜
K0 .5 Na0 .5 NbO3%BiFeO3%수열법%무연압전%참잡
K0 .5 Na0 .5 NbO3%BiFeO3%hydrothermal method%Lead-free piezoelectric%doping
以水热法制备的KNbO3,NaNbO 3,BiFeO 3(BF)粉体等为原料,采用常压烧结法在1065℃下烧结2 h制备了0.992K0.5 Na0.5 NbO3-0.008BiFeO 3无铅压电陶瓷,并研究了BiFeO 3掺杂对0.992K0.5 Na0.5 NbO3-0.008BiFeO 3无铅压电陶瓷结构和压电的影响.研究结果表明:BiFeO 3掺杂使K0.5 Na0.5 NbO3无铅压电陶瓷正交相减弱,晶粒尺寸由6μm 减小到1μm ;压电性能有一定提高,压电常数(d33)、机电耦合系数(kp )分别达到120 pC/N 和37.8,居里温度Tc由444.4℃减少至420.6℃.
以水熱法製備的KNbO3,NaNbO 3,BiFeO 3(BF)粉體等為原料,採用常壓燒結法在1065℃下燒結2 h製備瞭0.992K0.5 Na0.5 NbO3-0.008BiFeO 3無鉛壓電陶瓷,併研究瞭BiFeO 3摻雜對0.992K0.5 Na0.5 NbO3-0.008BiFeO 3無鉛壓電陶瓷結構和壓電的影響.研究結果錶明:BiFeO 3摻雜使K0.5 Na0.5 NbO3無鉛壓電陶瓷正交相減弱,晶粒呎吋由6μm 減小到1μm ;壓電性能有一定提高,壓電常數(d33)、機電耦閤繫數(kp )分彆達到120 pC/N 和37.8,居裏溫度Tc由444.4℃減少至420.6℃.
이수열법제비적KNbO3,NaNbO 3,BiFeO 3(BF)분체등위원료,채용상압소결법재1065℃하소결2 h제비료0.992K0.5 Na0.5 NbO3-0.008BiFeO 3무연압전도자,병연구료BiFeO 3참잡대0.992K0.5 Na0.5 NbO3-0.008BiFeO 3무연압전도자결구화압전적영향.연구결과표명:BiFeO 3참잡사K0.5 Na0.5 NbO3무연압전도자정교상감약,정립척촌유6μm 감소도1μm ;압전성능유일정제고,압전상수(d33)、궤전우합계수(kp )분별체도120 pC/N 화37.8,거리온도Tc유444.4℃감소지420.6℃.
In this study , Lead-free piezoelectric ceramics of the 0 .992 (Na0.5K0.5 ) NbO3-0 .008BiFeO3 were prepared at 1025℃ for 2h ,following the mixed pure KNbO3 (KN ) , NaNbO3 (NN) ,BiFeO3 (BF) powers which were prepared by a hydrothermal method .The phase structure and the electric properties of the ceramics were studied .It is found that the doping of BiFeO3 decreases the value of orthogonality of the KNN ceramics and decreases the grain size from 6 μm to 1 μm .Simultaneously the piezoelectric properties is increasing ,the piezoelectric constant d33 and planar mode electromechanical coupling coefficient kp reach to 120 Pc/N and 37 .8 ,the curie temperature Tc decreases from 444 .4 ℃ to 420 .6 ℃ .