CAJ | 학술논문

采用软模板法制备出多孔碳材料，以此为载体采用浸渍法制备了Ru/C催化剂，用于硝基苯与苯甲醇“一锅法”合成N-亚苄基苯胺中。利用XRD、SEM、TEM等方法对催化剂进行了表征。考察了Ru负载量对催化剂催化性能的影响，并对反应条件进行了优化。结果表明，Ru负载量为5.0wt%时Ru/C催化剂具有最佳的催化活性和选择性。在实验优化条件下反应22 h，硝基苯转化率为100%，N-亚苄基苯胺选择性可达94.1%。
채용연모판법제비출다공탄재료，이차위재체채용침지법제비료Ru/C최화제，용우초기분여분갑순“일과법”합성N-아변기분알중。이용XRD、SEM、TEM등방법대최화제진행료표정。고찰료Ru부재량대최화제최화성능적영향，병대반응조건진행료우화。결과표명，Ru부재량위5.0wt%시Ru/C최화제구유최가적최화활성화선택성。재실험우화조건하반응22 h，초기분전화솔위100%，N-아변기분알선택성가체94.1%。
A series of Ru/C catalysts were prepared by impregnation method using the porous carbon materials as support which was prepared by soft template method. The catalysts were used in the one-pot synthesis of N-benzalaniline from nitrobenzene (NB) and benzyl alcohol. The catalysts were characterized by XRD, SEM and TEM. The effect of Ru loading on the catalytic performance of Ru/C was studied, and the reaction conditions were optimized. The results showed that the Ru/C catalyst with 5.0wt% Ru loading exhibited the highest catalytic performance. Under the optimal reaction conditions, the N-benzalaniline selectivity reached 94.1%with 100%conversation of nitrobenzene after reaction 22 h.