湖北农业科学
湖北農業科學
호북농업과학
2014年
10期
2322-2324
,共3页
苗宗成%王义伟%李媛媛%张蕾
苗宗成%王義偉%李媛媛%張蕾
묘종성%왕의위%리원원%장뢰
水杨酸%环氧氯丙烷%酯化改性%红外光谱
水楊痠%環氧氯丙烷%酯化改性%紅外光譜
수양산%배양록병완%지화개성%홍외광보
salicylic acid%epichlorohydrin%esterification modification%IR-spectrum
为提高水杨酸在水中的溶解性提供新的改性方法,促进水杨酸在农业领域中的应用发展,以环氧氯丙烷、水杨酸为反应原料,得到了一种水杨酸的酯化改性产物。以产物收率为研究对象研究最佳反应条件,当环氧氯丙烷与水杨酸的摩尔比为1.5、反应溶剂为1,2-二氯乙烷、反应温度为50℃时,可获得的最大产物收率为87.5%。产物的结构采用傅里叶变换红外光谱进行表征,确定为目标化合物。
為提高水楊痠在水中的溶解性提供新的改性方法,促進水楊痠在農業領域中的應用髮展,以環氧氯丙烷、水楊痠為反應原料,得到瞭一種水楊痠的酯化改性產物。以產物收率為研究對象研究最佳反應條件,噹環氧氯丙烷與水楊痠的摩爾比為1.5、反應溶劑為1,2-二氯乙烷、反應溫度為50℃時,可穫得的最大產物收率為87.5%。產物的結構採用傅裏葉變換紅外光譜進行錶徵,確定為目標化閤物。
위제고수양산재수중적용해성제공신적개성방법,촉진수양산재농업영역중적응용발전,이배양록병완、수양산위반응원료,득도료일충수양산적지화개성산물。이산물수솔위연구대상연구최가반응조건,당배양록병완여수양산적마이비위1.5、반응용제위1,2-이록을완、반응온도위50℃시,가획득적최대산물수솔위87.5%。산물적결구채용부리협변환홍외광보진행표정,학정위목표화합물。
Salicylic acid as an important growth promoter for crops has broad applications in the field of agriculture.Using epichlorohydrin as material,a modified product of salicylic acid was prepared through esterification reaction.The structure of the product was characterized by Fourier transform infrared spectroscopy.The reaction conditions were optimized and the yield of the product was evalued.When the molar ratio of epichlorohydrin and salicylic acid was 1.5,the reaction solvent was 1,2-dichloroethane,the reaction temperature was 50℃,the maximum yield was 87.5%. This research will provide a new method for increasing the water-solubility of salicylic acid,and promote the application and development of salicylic acid in the field of agriculture.