功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
z2期
192-197
,共6页
铸造多晶硅%平行孪晶%定向凝固%生长机制
鑄造多晶硅%平行孿晶%定嚮凝固%生長機製
주조다정규%평행련정%정향응고%생장궤제
cast polysilicon%parallel twin%directional solidification%growth mechanism
近些年来由于低成本、低耗能和少污染等特点,铸造多晶硅已成为主要的光伏材料之一,越来越受到人们的广泛关注。但通过定向凝固工艺获得的粗大的晶体中存在大量的孪晶,认为孪晶就有可能对晶体生长起着主导作用。采用自行设计的真空电磁感应熔炼炉及定向凝固炉对冶金级多晶硅进行了真空条件下的定向凝固实验,通过对定向凝固铸锭的观察和分析并结合国内外其它研究机构在此方面的研究,对铸造多晶硅中平行孪晶的生长机制和小平面枝晶的生长机制进行了详细的分析和讨论。
近些年來由于低成本、低耗能和少汙染等特點,鑄造多晶硅已成為主要的光伏材料之一,越來越受到人們的廣汎關註。但通過定嚮凝固工藝穫得的粗大的晶體中存在大量的孿晶,認為孿晶就有可能對晶體生長起著主導作用。採用自行設計的真空電磁感應鎔煉爐及定嚮凝固爐對冶金級多晶硅進行瞭真空條件下的定嚮凝固實驗,通過對定嚮凝固鑄錠的觀察和分析併結閤國內外其它研究機構在此方麵的研究,對鑄造多晶硅中平行孿晶的生長機製和小平麵枝晶的生長機製進行瞭詳細的分析和討論。
근사년래유우저성본、저모능화소오염등특점,주조다정규이성위주요적광복재료지일,월래월수도인문적엄범관주。단통과정향응고공예획득적조대적정체중존재대량적련정,인위련정취유가능대정체생장기착주도작용。채용자행설계적진공전자감응용련로급정향응고로대야금급다정규진행료진공조건하적정향응고실험,통과대정향응고주정적관찰화분석병결합국내외기타연구궤구재차방면적연구,대주조다정규중평행련정적생장궤제화소평면지정적생장궤제진행료상세적분석화토론。
In recent years,cast polycrystalline silicon had become a one of major photovoltaic because of its low cost,low energy consumption and less pollution and other advantages and it received wide attention.However, there were a lot of twins in the coarse columnar grain obtained by directional solidification process.We believed that twin was likely to play a leading role on the crystal growth.The vacuum melting furnace and directional so-lidification furnace which were designed by us were used to refine metallurgical grade silicon (MG-Si)under vacuum conditions.The growth mechanism of parallel twins and small plane dendritic growth mechanisms in casting polycrystalline silicon were analyzed and discussed in detail based on the observation and analysis of di-rectional solidification test of our group and the research in this area of other research institutions at home and abroad.