中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2013年
12期
3423-3429
,共7页
肖玮%鲁雄刚%邹星礼%李重河%丁伟中
肖瑋%魯雄剛%鄒星禮%李重河%丁偉中
초위%로웅강%추성례%리중하%정위중
钛铁矿%镁%富氢气体%直接还原%耦合反应
鈦鐵礦%鎂%富氫氣體%直接還原%耦閤反應
태철광%미%부경기체%직접환원%우합반응
ilmenite%magnesium%hydrogen-rich gas%direct reduction%coupling reaction
利用大载荷热重分析仪、质谱仪、碳分析仪、SEM和XRD测定不同还原条件下钛铁矿(FeTiO 3)气基还原产物的质量损失率、钛和镁元素分布、微观结构及物相组成,研究富氢气体还原钛铁矿过程中各气体组分间的耦合作用机制。结果表明:在氢气还原过程中金属铁在颗粒外层聚集,并伴随着钛和镁两种元素的聚集形成致密层;富氢气体还原则不形成相应的致密层,金属铁以细小颗粒状较均匀地分布在颗粒内部,钛和镁也较为均匀地分散在整个颗粒内部。此外,富氢气体中的CO能在金属铁的表面形成一定量的表面碳,并能将H 2 O分子重新还原为氢气,从而提高了氢气在还原过程中的利用率。
利用大載荷熱重分析儀、質譜儀、碳分析儀、SEM和XRD測定不同還原條件下鈦鐵礦(FeTiO 3)氣基還原產物的質量損失率、鈦和鎂元素分佈、微觀結構及物相組成,研究富氫氣體還原鈦鐵礦過程中各氣體組分間的耦閤作用機製。結果錶明:在氫氣還原過程中金屬鐵在顆粒外層聚集,併伴隨著鈦和鎂兩種元素的聚集形成緻密層;富氫氣體還原則不形成相應的緻密層,金屬鐵以細小顆粒狀較均勻地分佈在顆粒內部,鈦和鎂也較為均勻地分散在整箇顆粒內部。此外,富氫氣體中的CO能在金屬鐵的錶麵形成一定量的錶麵碳,併能將H 2 O分子重新還原為氫氣,從而提高瞭氫氣在還原過程中的利用率。
이용대재하열중분석의、질보의、탄분석의、SEM화XRD측정불동환원조건하태철광(FeTiO 3)기기환원산물적질량손실솔、태화미원소분포、미관결구급물상조성,연구부경기체환원태철광과정중각기체조분간적우합작용궤제。결과표명:재경기환원과정중금속철재과립외층취집,병반수착태화미량충원소적취집형성치밀층;부경기체환원칙불형성상응적치밀층,금속철이세소과립상교균균지분포재과립내부,태화미야교위균균지분산재정개과립내부。차외,부경기체중적CO능재금속철적표면형성일정량적표면탄,병능장H 2 O분자중신환원위경기,종이제고료경기재환원과정중적이용솔。
Thermogravimetric analyzer, mass spectrometer, carbon analyzer, SEM and XRD were utilized to study the reduction product of ilmenite (FeTiO3). The mass loss, distribution of titanium and magnesium, micromorphology and phase transitions were investigated. The coupling reaction between different components of hydrogen-rich gas was also discussed. The results show that a dense layer forms inside ilmenite particle with the beneficiation of metal iron, titanium, and magnesium in the hydrogen reduction process. Unlike the hydrogen direct reduction, the dense layer can not form in the hydrogen-rich gaseous reduction. The metal iron in the form of granule type distributes evenly in the body of the particle, and titanium and magnesium also distribute in all particles. In addition, the CO in hydrogen-rich gas can be dissociated on the surface of metal iron which plays the role of catalyst. The surface carbon which is formed by the dissociation of CO can reduce H2O molecule again, so that the utilization of hydrogen can be elevated.