CAJ | 학술논문

以离子液体溴化(1-己基-3-甲基咪唑盐)作为电解质和掺杂剂采用电化学一步法制备了微纳米复合结构的聚(3,4-乙烯基二氧噻吩)薄膜,薄膜由槽内排布着纳米珠链的棒状结构组成。研究表明,通过控制电流密度的大小,可以调节棒状结构和珠状结构的平均直径。离子液体中的咪唑阳离子和对阴离子均掺杂到聚合物中,该薄膜具有可逆的电化学活性及水下超疏油特性。
이리자액체추화(1-기기-3-갑기미서염)작위전해질화참잡제채용전화학일보법제비료미납미복합결구적취(3,4-을희기이양새분)박막,박막유조내배포착납미주련적봉상결구조성。연구표명,통과공제전류밀도적대소,가이조절봉상결구화주상결구적평균직경。리자액체중적미서양리자화대음리자균참잡도취합물중,해박막구유가역적전화학활성급수하초소유특성。
Micro/nanostructured poly ( 3 , 4-ethylenedioxythiophene ) ( PEDOT ) films were fabricated by an electrochemical polymerization in the presence of ionic liquid ( 1-hexyl-3 methyllimidazolium bromide ) as the electrolyte and dopants. The PEDOT films consist of micro-rod structures that encompass the micro-groove structure, and the nano-chain structure arranged inside of the micro-groove structure. The width of micro-grooves and the beads on the nano-chains can be adjusted by changing the current density of polymerization. The results showed that PEDOT chain backbone was doped by both the anion( Br-) and cation( imidazolium) of ionic liquids. In addition, PEDOT film exhibited reversible electrochemical activity and underwater supero-leophobic properties, which could be used for the application of the underwater anti-fouling coating and con-trolled oil-water separation materials.