贵金属
貴金屬
귀금속
PRECIOUS METALS
2013年
z1期
167-170
,共4页
关俊卿%贺昕%陈峤%熊晓东%陈斐%吴松
關俊卿%賀昕%陳嶠%熊曉東%陳斐%吳鬆
관준경%하흔%진교%웅효동%진비%오송
金属材料%高温共烧%铂电极浆料%片式氧传感器
金屬材料%高溫共燒%鉑電極漿料%片式氧傳感器
금속재료%고온공소%박전겁장료%편식양전감기
metal material%high temperature co-sintering%platinum electrode paste%chip oxygen sensor
汽车所用的片式氧传感器需要多层高温共烧结制备,烧结温度大于1500℃,如此高的烧结温度对铂电极浆料的耐热性提出较高的要求,要求反应铂电极浆料有较高耐热性能,高温烧结收缩较小,反应电极有高致密性多孔层叠的结构进而使得铂电极-YSZ-气体三相界面增长,使得片式氧传感器的氧敏响应性能和催化性能显著提高;要求加热铂电极要有致密的结构,阻值稳定,连续性好,长时间通电不易烧断。传统的铂电极浆料烧结温度为800~1200℃,明显不能满足高温烧结的需要。本文研究制备了适用于高温烧结的铂反应电极浆料和铂加热电极浆料。
汽車所用的片式氧傳感器需要多層高溫共燒結製備,燒結溫度大于1500℃,如此高的燒結溫度對鉑電極漿料的耐熱性提齣較高的要求,要求反應鉑電極漿料有較高耐熱性能,高溫燒結收縮較小,反應電極有高緻密性多孔層疊的結構進而使得鉑電極-YSZ-氣體三相界麵增長,使得片式氧傳感器的氧敏響應性能和催化性能顯著提高;要求加熱鉑電極要有緻密的結構,阻值穩定,連續性好,長時間通電不易燒斷。傳統的鉑電極漿料燒結溫度為800~1200℃,明顯不能滿足高溫燒結的需要。本文研究製備瞭適用于高溫燒結的鉑反應電極漿料和鉑加熱電極漿料。
기차소용적편식양전감기수요다층고온공소결제비,소결온도대우1500℃,여차고적소결온도대박전겁장료적내열성제출교고적요구,요구반응박전겁장료유교고내열성능,고온소결수축교소,반응전겁유고치밀성다공층첩적결구진이사득박전겁-YSZ-기체삼상계면증장,사득편식양전감기적양민향응성능화최화성능현저제고;요구가열박전겁요유치밀적결구,조치은정,련속성호,장시간통전불역소단。전통적박전겁장료소결온도위800~1200℃,명현불능만족고온소결적수요。본문연구제비료괄용우고온소결적박반응전겁장료화박가열전겁장료。
Chip oxygen sensor for automobiles needs multi-layer high temperature co-sintering processing, the sintering temperature is higher than 1500 , the high sinteri℃ ng temperature requires higher heat resistance and small shrinkage during sintering of platinum electrode pastes. Because of the structure of the reactive electrode has high density porous laminated, and then makes the platinum electrode- YSZ- gas phase interface significant growth, makes the planar oxygen sensor’s oxygen sensitive properties and catalytic performance improved significantly. The structure of the heating platinum electrode is dense, stable resistance, good continuity, long time power is not easy to burn. The sintering temperature of traditional platinum electrode pastes is 800~1200 ,℃ it obviously can not meet the need of high temperature sintering. In this paper the reactive platinum electrode paste and heating platinum electrode paste suitable for high temperature sintering were prepared.