伊犁师范学院学报(自然科学版)
伊犛師範學院學報(自然科學版)
이리사범학원학보(자연과학판)
JOURNAL OF ILI NORMAL UNIVERSITY
2013年
4期
55-60
,共6页
徐凡华%衡晓%张晓媛%鹿桂花%周恒为
徐凡華%衡曉%張曉媛%鹿桂花%週恆為
서범화%형효%장효원%록계화%주항위
蛋白质水凝胶%脱水变性%裂纹
蛋白質水凝膠%脫水變性%裂紋
단백질수응효%탈수변성%렬문
protein hydrogel%dehydrating degeneration%crack
通过扫描电子显微镜,对附着在不锈钢衬底上的天然蛋白质水凝胶--鸡蛋清脱水固化变性过程中产生的裂纹进行测量与分析.结果表明,固化的鸡蛋清内部存在呈网状的裂纹结构,即裂纹将样品分割为较小的独立区域;在约0.1至1mm左右的尺度,裂纹结构具有自相似性;在更小的尺度出现楔子状的裂纹,失去上述自相似特征.楔状裂纹并不直,在其端点会有更小的裂纹.在楔状裂纹的边界和尖端的亮度较高,这可能是内应力较大或者是存在更小裂纹的区域;在靠近衬底没有裂纹的边缘区域,固化蛋清以阶梯形状和衬底结合,与衬底之间没有间隙.
通過掃描電子顯微鏡,對附著在不鏽鋼襯底上的天然蛋白質水凝膠--鷄蛋清脫水固化變性過程中產生的裂紋進行測量與分析.結果錶明,固化的鷄蛋清內部存在呈網狀的裂紋結構,即裂紋將樣品分割為較小的獨立區域;在約0.1至1mm左右的呎度,裂紋結構具有自相似性;在更小的呎度齣現楔子狀的裂紋,失去上述自相似特徵.楔狀裂紋併不直,在其耑點會有更小的裂紋.在楔狀裂紋的邊界和尖耑的亮度較高,這可能是內應力較大或者是存在更小裂紋的區域;在靠近襯底沒有裂紋的邊緣區域,固化蛋清以階梯形狀和襯底結閤,與襯底之間沒有間隙.
통과소묘전자현미경,대부착재불수강츤저상적천연단백질수응효--계단청탈수고화변성과정중산생적렬문진행측량여분석.결과표명,고화적계단청내부존재정망상적렬문결구,즉렬문장양품분할위교소적독립구역;재약0.1지1mm좌우적척도,렬문결구구유자상사성;재경소적척도출현설자상적렬문,실거상술자상사특정.설상렬문병불직,재기단점회유경소적렬문.재설상렬문적변계화첨단적량도교고,저가능시내응력교대혹자시존재경소렬문적구역;재고근츤저몰유렬문적변연구역,고화단청이계제형상화츤저결합,여츤저지간몰유간극.
The cracks of a natural protein hydrogel, egg white after dehydrating degeneration and solidification on the stainless steel substrate were measured and analyzed by the scanning electron microscopy (SEM) in this paper. The results show that there are mesh crack structures within solidifying egg white, i.e. the sample was divided into smaller individual regions by cracks;the crack structures have self-similarity one the scale of about 0.1 to 1mm;wedge-shaped cracks appear one smaller scale, and the self-similarity disappears. The wedge cracks are not straight, and there are smaller cracks near their endpoint. The image brightness of tips and boundaries of wedge cracks is high, which may be due to internal stress being large and/or the existence of smaller crack regions;in the edge regions without cracks near the substrate, the solidifying egg white connects with the substrate in a step shape, and there is not any gap between them.