CAJ | 학술논문

论述了减排CO2的重要性，概述了CO2化学利用的主要方法，综述了CO2的3种氨化反应，即氨化反应生成碳酸氢铵、尿素和三聚氰酸，重点介绍了 CO2氨化反应生成三聚氰酸，对该反应进行了热力学分析，叙述了其反应的特点，得出 CO2氨化合成三聚氰酸等固体产品是一条比较可行的 CO2化学利用路线。氨化合成三聚氰酸不仅可以实现CO2的封存，而且能够实现CO2的高值有效利用，对解决CO2减排具有重要意义。认为将氨化反应与煤化工产业相结合，可以有效减少二氧化碳的排放强度，具有广阔的发展前景。
논술료감배CO2적중요성，개술료CO2화학이용적주요방법，종술료CO2적3충안화반응，즉안화반응생성탄산경안、뇨소화삼취청산，중점개소료 CO2안화반응생성삼취청산，대해반응진행료열역학분석，서술료기반응적특점，득출 CO2안화합성삼취청산등고체산품시일조비교가행적 CO2화학이용로선。안화합성삼취청산불부가이실현CO2적봉존，이차능구실현CO2적고치유효이용，대해결CO2감배구유중요의의。인위장안화반응여매화공산업상결합，가이유효감소이양화탄적배방강도，구유엄활적발전전경。
The importance of CO2 emission reduction is discussed,and the main methods of chemical utilization of CO2 is outlined. Three ways of ammonolysis reaction of carbon dioxide are reviewed. Ammonolysis reaction produces ammonium bicarbonate , urea and cyanuric acid. Production of cyanuric acid by ammonolysis of carbon dioxide is highlighted,and the thermodynamics is analyzed. The reaction characteristics are described,and ammonolysis of carbon dioxide to produce cyanuric acid and other solid products is a feasible way for chemicalutulization of carbon dioxide. Not only carbon dioxide can be sealed up,but also high added value products can be obtained. Combination of ammonolysis reaction and coal chemical industry will reduce emission of carbon dioxide effectively, and has a broad prospect.