化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
1期
204-208
,共5页
陈燕敏%孙彩霞%吴晋英%黄长山
陳燕敏%孫綵霞%吳晉英%黃長山
진연민%손채하%오진영%황장산
环保%阻垢%缓蚀%聚环氧琥珀酸%协同效应
環保%阻垢%緩蝕%聚環氧琥珀痠%協同效應
배보%조구%완식%취배양호박산%협동효응
environmentally friendly%scale inhibition%corrosion inhibition%polyepoxysuccinic acid%synergistic effect
以聚环氧琥珀酸(PESA)、聚丙烯酸(PAA)、水解聚马来酸酐(HPMA)、苯并三氮唑(BTA)为原料,研制出一种新型具有环保功能的复合型高效阻垢缓蚀剂。通过正交试验确定该阻垢缓蚀剂中各组分的最佳浓度为:PESA(1.0 mg/L)/PAA(1.0 mg/L)/HPMA (0.6 mg/L)/BTA(0.5 mg/L)。分别采用鼓泡法、电化学试验和旋转挂片腐蚀试验研究了其阻垢缓蚀性能。试验结果表明,该阻垢缓蚀剂的阻垢率为92%,对A3碳钢、铜、不锈钢的缓蚀率分别达到了83%、97%、99%,动态模拟试验结果也显示该阻垢缓蚀剂满足循环冷却水运行要求。
以聚環氧琥珀痠(PESA)、聚丙烯痠(PAA)、水解聚馬來痠酐(HPMA)、苯併三氮唑(BTA)為原料,研製齣一種新型具有環保功能的複閤型高效阻垢緩蝕劑。通過正交試驗確定該阻垢緩蝕劑中各組分的最佳濃度為:PESA(1.0 mg/L)/PAA(1.0 mg/L)/HPMA (0.6 mg/L)/BTA(0.5 mg/L)。分彆採用鼓泡法、電化學試驗和鏇轉掛片腐蝕試驗研究瞭其阻垢緩蝕性能。試驗結果錶明,該阻垢緩蝕劑的阻垢率為92%,對A3碳鋼、銅、不鏽鋼的緩蝕率分彆達到瞭83%、97%、99%,動態模擬試驗結果也顯示該阻垢緩蝕劑滿足循環冷卻水運行要求。
이취배양호박산(PESA)、취병희산(PAA)、수해취마래산항(HPMA)、분병삼담서(BTA)위원료,연제출일충신형구유배보공능적복합형고효조구완식제。통과정교시험학정해조구완식제중각조분적최가농도위:PESA(1.0 mg/L)/PAA(1.0 mg/L)/HPMA (0.6 mg/L)/BTA(0.5 mg/L)。분별채용고포법、전화학시험화선전괘편부식시험연구료기조구완식성능。시험결과표명,해조구완식제적조구솔위92%,대A3탄강、동、불수강적완식솔분별체도료83%、97%、99%,동태모의시험결과야현시해조구완식제만족순배냉각수운행요구。
A new kind of efficient environmentally-friendly composite scale and corrosion inhibitor consisting of polyepoxysuccinic acid (PESA) , polyacrylic acid (PAA) , hydrolyzed polymaleic anhydride (HPMA) , benzotriazole (BTA) was developed. The optimal concentrations of such components obtained from orthogonal experiments were PESA(1.0 mg/L)/PAA(1.0 mg/L)/HPMA (0.6 mg/L)/BTA(0.5 mg/L). Its scale inhibition and corrosion inhibition performance was studied with bubble method,electrochemical experiment and rotary weight loss/hanging-piece corrosion experiment. The scale inhibiting rate and corrosion inhibiting rates for A3 carbon steel,copper,stainless steel of the scale and corrosion inhibitor were 92%and 83%,97%,99%,respectively. Further dynamic simulated test also indicated that the scale and corrosion inhibitor meet the demand of circulating cooling water.