稀土学报(英文版)
稀土學報(英文版)
희토학보(영문판)
JOURNAL OF RARE EARTHS
2014年
1期
1-4
,共4页
余金秋%崔磊%何华强%颜世宏%胡运生%吴浩
餘金鞦%崔磊%何華彊%顏世宏%鬍運生%吳浩
여금추%최뢰%하화강%안세굉%호운생%오호
Raman spectroscopy%rare earth sesquioxides%laser-excited luminescence%rare earths
Raman spectra of a series of cubic rare earth sesquioxides RE2O3 (RE=Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Sc and Y) were investigated by Raman spectroscopy with both 532 and 785 nm laser lines. Abundant additional bands due to laser-excited lumines-cence were observed. For Eu2O3, Dy2O3, Ho2O3, Er2O3, Tm2O3 and Yb2O3, the luminescence mainly came from the intrinsic trivalent lanthanide ions, while for Gd2O3, Lu2O3, Sc2O3 and Y2O3, their luminescence were attributed to the trace impurities of other lumines-cent lanthanide ions such as Eu3+, Nd3+and Er3+. This investigation confirmed Raman spectroscopy as a useful tool for detecting trace luminescent lanthanide impurities.