CAJ | 학술논문

探索两步法合成1-丁基-3-甲基咪唑甘氨酸离子液体（[ bmim] Gly）的反应条件。第一步，采用阴离子树脂静态交换法由1-丁基-3-甲基咪唑溴盐（[ bmim ] Br ）与强碱性阴离子树脂生成中间产物1-丁基-3-甲基咪唑氢氧化物（[bmim]OH），通过单因素实验获得其最佳交换条件；第二步，[ bmim ] OH 与甘氨酸（ Gly ）反应，经脱水、洗涤后得目标产物。对产物进行核磁（1H NMR）和红外（IR）表征，结果表明产品纯度较高。与动态合成法相比，静态法合成[ bmim] Gly操作简便，节水省时，有助于实现氨基酸离子液体合成过程的绿色化和工业化。
탐색량보법합성1-정기-3-갑기미서감안산리자액체（[ bmim] Gly）적반응조건。제일보，채용음리자수지정태교환법유1-정기-3-갑기미서추염（[ bmim ] Br ）여강감성음리자수지생성중간산물1-정기-3-갑기미서경양화물（[bmim]OH），통과단인소실험획득기최가교환조건；제이보，[ bmim ] OH 여감안산（ Gly ）반응，경탈수、세조후득목표산물。대산물진행핵자（1H NMR）화홍외（IR）표정，결과표명산품순도교고。여동태합성법상비，정태법합성[ bmim] Gly조작간편，절수성시，유조우실현안기산리자액체합성과정적록색화화공업화。
The 1-butyl-3-methylimidazolium glycine acid salt([bmim]Gly) was prepared by two steps.The first step,the intermediary,1-butyl-3-methylimidazolium hydroxide ([bmim]OH) was prepared by 1-butyl-3-methyl im-idazolium bromide ( [ bmim ] Br ) through a static anion ion exchange. The optimum reaction conditions were obtained by single factor experiments.The second step,the [ bmim] OH and glycine were mixed and reacted,then were dried under vacuum and washed with methanol,to form high purity product.The structure of product was con-firmed and characterized by 1H NMR and IR.Compared with dynamic preparation method,the proposed static meth-od is simple in operation and rapid in production rate,and consumes less leaching water and energy,so it promotes the preparation of the amino acid ionic liquid in a more green and industrialized direction.