化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
2期
711-717
,共7页
沈伯雄%蔡记%陈建宏%李卓%何川
瀋伯雄%蔡記%陳建宏%李卓%何川
침백웅%채기%진건굉%리탁%하천
碘改性黏土%溴改性黏土%脱汞
碘改性黏土%溴改性黏土%脫汞
전개성점토%추개성점토%탈홍
KBr modified clay%KI modified clay%elemental mercury removal
黏土是一种非常廉价的天然矿物,为了考察溴和碘改性黏土(膨润土)脱除烟气中单质汞的特性,采用浸渍法分别制备了KBr和KI改性黏土(KBr-clay和KI-clay)。在固定床吸附实验台上进行了脱除Hg0的实验研究,考察不同的负载量、吸附温度以及烟气中SO2和水蒸气等对KI-clay和KBr-clay脱除单质汞的影响。研究结果表明:改性后黏土的比表面积、孔隙结构未发生显著的改变,表面官能团也没有发生本质的变化。KI-clay和KBr-clay脱汞能力大大提高,在同等实验条件下,KI-clay脱汞性能优于KBr-clay。研究表明单质汞在改性黏土表面产生了化学吸附,烟气中低浓度SO2的存在对汞脱除有一定的促进作用,在相同的实验条件下,SO2对KBr-clay促进作用更加明显,但水蒸气在低温下对脱汞具有很强的抑制作用,提高吸附温度可以消弱水蒸气的负面影响。
黏土是一種非常廉價的天然礦物,為瞭攷察溴和碘改性黏土(膨潤土)脫除煙氣中單質汞的特性,採用浸漬法分彆製備瞭KBr和KI改性黏土(KBr-clay和KI-clay)。在固定床吸附實驗檯上進行瞭脫除Hg0的實驗研究,攷察不同的負載量、吸附溫度以及煙氣中SO2和水蒸氣等對KI-clay和KBr-clay脫除單質汞的影響。研究結果錶明:改性後黏土的比錶麵積、孔隙結構未髮生顯著的改變,錶麵官能糰也沒有髮生本質的變化。KI-clay和KBr-clay脫汞能力大大提高,在同等實驗條件下,KI-clay脫汞性能優于KBr-clay。研究錶明單質汞在改性黏土錶麵產生瞭化學吸附,煙氣中低濃度SO2的存在對汞脫除有一定的促進作用,在相同的實驗條件下,SO2對KBr-clay促進作用更加明顯,但水蒸氣在低溫下對脫汞具有很彊的抑製作用,提高吸附溫度可以消弱水蒸氣的負麵影響。
점토시일충비상렴개적천연광물,위료고찰추화전개성점토(팽윤토)탈제연기중단질홍적특성,채용침지법분별제비료KBr화KI개성점토(KBr-clay화KI-clay)。재고정상흡부실험태상진행료탈제Hg0적실험연구,고찰불동적부재량、흡부온도이급연기중SO2화수증기등대KI-clay화KBr-clay탈제단질홍적영향。연구결과표명:개성후점토적비표면적、공극결구미발생현저적개변,표면관능단야몰유발생본질적변화。KI-clay화KBr-clay탈홍능력대대제고,재동등실험조건하,KI-clay탈홍성능우우KBr-clay。연구표명단질홍재개성점토표면산생료화학흡부,연기중저농도SO2적존재대홍탈제유일정적촉진작용,재상동적실험조건하,SO2대KBr-clay촉진작용경가명현,단수증기재저온하대탈홍구유흔강적억제작용,제고흡부온도가이소약수증기적부면영향。
Clay is a kind of cheap natural minerals in China. In order to study their performance for removal of elemental mercury in flue gas, the clays were modified by impregnating KBr and KI to prepare KBr-clay and KI-clay. A series of bench adsorption tests was carried out in a fixed bed to examine the removal efficiency of elemental mercury from simulated flue gas by KBr-clay and KI-clay. The effect of halogen loadings, adsorbent temperatures and the flue gas components (SO2 and H2O) on the performance was studied. The result showed that the modification did not much change the specific surface area and the pore structure of the clays, while there was little variation also in the surface functional groups. The sorption capacity of elemental mercury by KBr-clay and KI-clay was drastically improved, and it is of better activity for KI-clay than for KBr-clay under the same experimental conditions. The chemical adsorption played a dominant pole in the process of the elemental mercury removal. SO2 was found to have a promotional effect on elemental mercury adsorption, and the promotional effect of SO2 was more apparent for KBr-clay. H2O vapor exhibited a inhibitory effect on elemental mercury adsorption, but the effect decreased with the raising reaction temperature.