CAJ | 학술논문

采用分子动力学方法对偏钒酸铯(CsVO 3)与3种聚合物的表面吸附能进行了模拟计算。根据计算结果,选择苯乙烯-甲基丙烯酸甲酯共聚物(P (S-MMA))作为包覆层,采用超声偶联-原位分散聚合法制备了CsVO 3/P(S-MMA)复合荧光微球,进而旋涂成膜,并对其结构与性能进行表征。结果表明,Cs-VO 3/P(S-MMA)复合材料尽管发光强度有所减弱,但其避免了CsVO 3粉体的团聚,扩展了 CsVO 3在柔性发光与显示器件中的应用。
채용분자동역학방법대편범산색(CsVO 3)여3충취합물적표면흡부능진행료모의계산。근거계산결과,선택분을희-갑기병희산갑지공취물(P (S-MMA))작위포복층,채용초성우련-원위분산취합법제비료CsVO 3/P(S-MMA)복합형광미구,진이선도성막,병대기결구여성능진행표정。결과표명,Cs-VO 3/P(S-MMA)복합재료진관발광강도유소감약,단기피면료CsVO 3분체적단취,확전료 CsVO 3재유성발광여현시기건중적응용。
The interaction manners between three polymers and CsVO 3 crystal surfaces were simulated.On the basis of theoretical calculation CsVO 3/P(S-MMA)powder was prepared by ultrasonic-coupling and in-situ dis-persion polymerization.And its film was obtained by spin coating.Their structure and properties were charac-terized.Results show that direct fabrication of the CsVO 3/P(S-MMA)would be advantageous not only to avoid particle aggregation but also to further expand potential applications for flexible devices.