化学研究与应用
化學研究與應用
화학연구여응용
CHEMICAL RESEARCH AND APPLICATION
2014年
1期
121-124
,共4页
何忠义%雷娟红%卢慧%熊丽萍%仇建伟%伏喜胜
何忠義%雷娟紅%盧慧%熊麗萍%仇建偉%伏喜勝
하충의%뢰연홍%로혜%웅려평%구건위%복희성
噻二唑衍生物%摩擦学性能%研究
噻二唑衍生物%摩抆學性能%研究
새이서연생물%마찰학성능%연구
thiadiazole derivative%tribological property%study
合成了一种高硫含羟基和黄原酸的噻二唑衍生物(ESP),利用四球摩擦磨损试验机考察了其在Corda 3970基础油中的摩擦磨损性能,表明所合成的添加剂能够有效的提高Corda 3970基础油的极压和抗磨性能,并且在一定的浓度范围内随着浓度的增加,其抗磨减摩性能增加。通过扫描电镜( SEM)分析了钢球表面形貌及元素分布,发现其主导作用的是边界膜中存在S、O、N活性元素,它们形成复合膜是添加剂具有摩擦学性能的主要原因。
閤成瞭一種高硫含羥基和黃原痠的噻二唑衍生物(ESP),利用四毬摩抆磨損試驗機攷察瞭其在Corda 3970基礎油中的摩抆磨損性能,錶明所閤成的添加劑能夠有效的提高Corda 3970基礎油的極壓和抗磨性能,併且在一定的濃度範圍內隨著濃度的增加,其抗磨減摩性能增加。通過掃描電鏡( SEM)分析瞭鋼毬錶麵形貌及元素分佈,髮現其主導作用的是邊界膜中存在S、O、N活性元素,它們形成複閤膜是添加劑具有摩抆學性能的主要原因。
합성료일충고류함간기화황원산적새이서연생물(ESP),이용사구마찰마손시험궤고찰료기재Corda 3970기출유중적마찰마손성능,표명소합성적첨가제능구유효적제고Corda 3970기출유적겁압화항마성능,병차재일정적농도범위내수착농도적증가,기항마감마성능증가。통과소묘전경( SEM)분석료강구표면형모급원소분포,발현기주도작용적시변계막중존재S、O、N활성원소,타문형성복합막시첨가제구유마찰학성능적주요원인。
A high sulfur hydroxyl and xanthate-containing thiadiazole derivative( ESP) was synthesized in the text,and it’s friction and wear performance of composition ESP in Corda 3970 were investing by four-ball tester. Results indicated that the synthetic addi-tive can effectively improve the Corda 3970 base oil extreme pressure and antiwear performance,and along with the concentration in-creasing,the anti-wear and anti-friction performance increase at a given concentration range. The surface morphology and element distribution of worn steel ball surface were analyzed by using scanning electron microscopy( SEM) ,and it was found that the bound-ary film which containing S,O,N elements,is the main reason for the additive which possesses the tribological performance.