化学研究与应用
化學研究與應用
화학연구여응용
CHEMICAL RESEARCH AND APPLICATION
2014年
1期
23-27
,共5页
王储备%周建伟%褚亮亮%刘建枫
王儲備%週建偉%褚亮亮%劉建楓
왕저비%주건위%저량량%류건풍
溴化银%石墨烯%光催化%等离子体效应
溴化銀%石墨烯%光催化%等離子體效應
추화은%석묵희%광최화%등리자체효응
silver bromide%graphene%photocatalysis%plasmon resonance effect
以石墨烯为载体,通过化学沉积与光还原法制备了具有等离子体共振效应的Ag-AgBr/RGO可见光催化剂。采用XRD 及 UV-Vis 吸收光谱对催化剂进行结构与性能表征,并考察其降解甲基橙溶液的光催化性能。研究结果表明,在可见光下照射60min,催化剂对10 mg·L-1甲基橙溶液的降解率达91%。由于表面金属的等离子体共振效应和石墨烯的协同作用,石墨烯为载体的催化剂的可见光催化活性比氧化铝为载体时高。
以石墨烯為載體,通過化學沉積與光還原法製備瞭具有等離子體共振效應的Ag-AgBr/RGO可見光催化劑。採用XRD 及 UV-Vis 吸收光譜對催化劑進行結構與性能錶徵,併攷察其降解甲基橙溶液的光催化性能。研究結果錶明,在可見光下照射60min,催化劑對10 mg·L-1甲基橙溶液的降解率達91%。由于錶麵金屬的等離子體共振效應和石墨烯的協同作用,石墨烯為載體的催化劑的可見光催化活性比氧化鋁為載體時高。
이석묵희위재체,통과화학침적여광환원법제비료구유등리자체공진효응적Ag-AgBr/RGO가견광최화제。채용XRD 급 UV-Vis 흡수광보대최화제진행결구여성능표정,병고찰기강해갑기등용액적광최화성능。연구결과표명,재가견광하조사60min,최화제대10 mg·L-1갑기등용액적강해솔체91%。유우표면금속적등리자체공진효응화석묵희적협동작용,석묵희위재체적최화제적가견광최화활성비양화려위재체시고。
The surface plasmon resonance photocatalyst of Ag-AgBr/RGO was synthesized by chemical precipitation and photochem-ical reduction method. The samples were characterized by XRD and UV-Vis spectroscopy. The photocatalytic properties of catalyst were studied with helianthine pollutant degraded under a visible light source. The results showed that the degradation rate of 10 mg ·L-1 helianthine reached more than 91%under 60 min visible light irradiation. Because of synergies between plasmon resonance effect of nano-siliver and the RGO,the catalysts have high activity.