CAJ | 학술논문

以未经水洗、干燥处理的聚二甲基硅烷粗产物为原料，常压裂解合成聚碳硅烷（PCS），通过FT-IR、GPC和TGA对PCS的结构和性能进行表征，测试结果与“Yajima法”制备的聚碳硅烷“PC-470”相近。与“Yajima法”相比较，PCS合成工艺简单、合成周期短、生产成本低、环境污染少，适宜于产业化放大生产。
이미경수세、간조처리적취이갑기규완조산물위원료，상압렬해합성취탄규완（PCS），통과FT-IR、GPC화TGA대PCS적결구화성능진행표정，측시결과여“Yajima법”제비적취탄규완“PC-470”상근。여“Yajima법”상비교，PCS합성공예간단、합성주기단、생산성본저、배경오염소，괄의우산업화방대생산。
Useing polydimethylsilane untreated with water-washing and drying process as material, polycar-bosilane precursor is synthesized by normal pressure pyrolysis. Its structure and property are characterized by FT-IR, GPC and TG, testing datas are very close to those of PC-470 prepared by Yajima method.Compared with Yajima method,the synthetic method has many advantages such as simple process,short pro-duction cycle,low cost and less contamination,and is suitable for industrial production.