化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2012年
7期
1493-1500
,共8页
顾卫荣%周明吉%马薇%王玉丽
顧衛榮%週明吉%馬薇%王玉麗
고위영%주명길%마미%왕옥려
脱硝%选择性催化还原%氮氧化物%催化剂%工业化
脫硝%選擇性催化還原%氮氧化物%催化劑%工業化
탈초%선택성최화환원%담양화물%최화제%공업화
flue gas denitration%selective catalytic reduction(SCR)%NOx%catalyst%industrialization
选择性催化还原(SCR)是目前控制氮氧化物排放的主要技术,该技术具有选择性好、脱硝效率高、不造成二次污染等优点。本文对SCR技术及其催化剂进行了综述,重点介绍了钒钛催化剂、贵金属催化剂、金属氧化物催化剂及沸石分子筛型催化剂的研究进展,并对国内外脱硝催化剂的工业化现状及催化剂的影响因素进行了分析,最后指出我国脱硝催化剂的发展应以提高催化剂寿命、开发新型催化剂(以复合金属氧化物催化剂和新型钒基催化剂为主)及新工艺为方向进行。
選擇性催化還原(SCR)是目前控製氮氧化物排放的主要技術,該技術具有選擇性好、脫硝效率高、不造成二次汙染等優點。本文對SCR技術及其催化劑進行瞭綜述,重點介紹瞭釩鈦催化劑、貴金屬催化劑、金屬氧化物催化劑及沸石分子篩型催化劑的研究進展,併對國內外脫硝催化劑的工業化現狀及催化劑的影響因素進行瞭分析,最後指齣我國脫硝催化劑的髮展應以提高催化劑壽命、開髮新型催化劑(以複閤金屬氧化物催化劑和新型釩基催化劑為主)及新工藝為方嚮進行。
선택성최화환원(SCR)시목전공제담양화물배방적주요기술,해기술구유선택성호、탈초효솔고、불조성이차오염등우점。본문대SCR기술급기최화제진행료종술,중점개소료범태최화제、귀금속최화제、금속양화물최화제급비석분자사형최화제적연구진전,병대국내외탈초최화제적공업화현상급최화제적영향인소진행료분석,최후지출아국탈초최화제적발전응이제고최화제수명、개발신형최화제(이복합금속양화물최화제화신형범기최화제위주)급신공예위방향진행。
Selective catalytic reduction(SCR) has been the mainstream technology to control emissions of NOx.This tecnology has numbers of advantages,such as extrodinary selectivity,high denitration and no secondary pollution.In this paper,the research progress of SCR and the catalysts was presented.The vanadium-titanium catalysts,noble metal catalysts,metal oxide catalysts and zeolite molecular were focused.The situation of the industrialization of the De-NOx catalyst and the main factors of catalysts was analyzed.Finally the development of De-NOx catalyst should be to improve the catalyst life,product the new catalysts(especially the mixed metal oxide catalysts and the new vanadiumt-based catalysts) and new technology direction.