CAJ | 학술논문

含磷阻燃剂具有低烟无毒、阻燃效果好的特点,是典型的无卤阻燃剂。本文阐述了含磷阻燃剂的阻燃机理,综述了将反应型含磷阻燃剂引入聚氨酯、环氧树脂和丙烯酸树脂等体系中所采用的不同改性方法,这些反应型阻燃聚合物均是主链或侧链含磷。本文还对近几年来国内外关于含磷阻燃剂在这些体系中的应用研究进展进行了概述,提出未来应加深对阻燃剂协同机理及含磷阻燃剂水性化和光固化的研究。
함린조연제구유저연무독、조연효과호적특점,시전형적무서조연제。본문천술료함린조연제적조연궤리,종술료장반응형함린조연제인입취안지、배양수지화병희산수지등체계중소채용적불동개성방법,저사반응형조연취합물균시주련혹측련함린。본문환대근궤년래국내외관우함린조연제재저사체계중적응용연구진전진행료개술,제출미래응가심대조연제협동궤리급함린조연제수성화화광고화적연구。
Phosphorus-containing flame retardant,which exhibits the characteristics of low smoke,non-toxic and good flame retardancy,is a significant type of halogen-free flame retardants.In this paper,we described the mechanism of phosphorus-containing flame retardant,and introduced the different modification methods to incorporate phosphorus into the main chain or side chain of polymer,especially in the application of polyurethane,epoxy and acrylic resin.In addition,we reviewed the development of reactive phosphorus-containing flame retardant in recent years.Finally,the suggestions for further study on the synergistic mechanism of flame retardants as well as the development of the waterborne and UV-curable flame retardant polymer were proposed.