化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2012年
9期
1885-1890
,共6页
磁稳流化床%磁性载体%基础研究
磁穩流化床%磁性載體%基礎研究
자은류화상%자성재체%기출연구
magnetically stabilized fluidized bed(MSFB)%magnetic carrier%basic research
磁稳流化床(MSFB)作为一种新型反应器,兼具固定床和流化床的众多优点,具有巨大的应用前景。本文综述了MSFB近年来在基础研究和应用上取得的进展。基础研究方面主要介绍了磁场强度和液相流速对床层结构的影响,以及床层空隙率、操作稳定性和传递特性等研究情况;应用方面介绍了MSFB在生物化工、能源和环境工程等领域的应用。最后分析了MSFB目前存在的不足,如对于一定的反应体系未找到相应合适的磁性催化剂、操作温度高于磁性载体的居里温度时,MSFB将无法操作、磁场发生装置释放出大量的热量对磁性载体和反应过程产生影响、难以确定稳定操作区域。并指出其今后的主要研究方向为磁性载体催化剂的研究与开发及对MSFB的稳定性判据、传热、传质、强化反应过程机理、反应器放大规律、工业化应用装置设计等方面的研究。
磁穩流化床(MSFB)作為一種新型反應器,兼具固定床和流化床的衆多優點,具有巨大的應用前景。本文綜述瞭MSFB近年來在基礎研究和應用上取得的進展。基礎研究方麵主要介紹瞭磁場彊度和液相流速對床層結構的影響,以及床層空隙率、操作穩定性和傳遞特性等研究情況;應用方麵介紹瞭MSFB在生物化工、能源和環境工程等領域的應用。最後分析瞭MSFB目前存在的不足,如對于一定的反應體繫未找到相應閤適的磁性催化劑、操作溫度高于磁性載體的居裏溫度時,MSFB將無法操作、磁場髮生裝置釋放齣大量的熱量對磁性載體和反應過程產生影響、難以確定穩定操作區域。併指齣其今後的主要研究方嚮為磁性載體催化劑的研究與開髮及對MSFB的穩定性判據、傳熱、傳質、彊化反應過程機理、反應器放大規律、工業化應用裝置設計等方麵的研究。
자은류화상(MSFB)작위일충신형반응기,겸구고정상화류화상적음다우점,구유거대적응용전경。본문종술료MSFB근년래재기출연구화응용상취득적진전。기출연구방면주요개소료자장강도화액상류속대상층결구적영향,이급상층공극솔、조작은정성화전체특성등연구정황;응용방면개소료MSFB재생물화공、능원화배경공정등영역적응용。최후분석료MSFB목전존재적불족,여대우일정적반응체계미조도상응합괄적자성최화제、조작온도고우자성재체적거리온도시,MSFB장무법조작、자장발생장치석방출대량적열량대자성재체화반응과정산생영향、난이학정은정조작구역。병지출기금후적주요연구방향위자성재체최화제적연구여개발급대MSFB적은정성판거、전열、전질、강화반응과정궤리、반응기방대규률、공업화응용장치설계등방면적연구。
Magnetically stabilized fluidized bed(MSFB) is a new type of reactor,which combines the advantages of both fixed bed and traditional fluidized bed,and has a great application prospect.In this paper,the progress of basic research and application of MSFB is reviewed.The basic research includes effects of fluid flow rate and magnetic field intensity on fluidization behavior of the magnetic particles in the column,bed voidage,operation stability and transfer characteristics.The application fields include biochemical engineering,energy and environmental engineering.Finally,the existing drawbacks of MSFB are presented.It remains difficult to find the relevant magnetic catalyst in a specific reaction system.MSFB can not be operated at a temperature higher than the Curie temperature of magnetic carrier.The heat generated by the magnetic field generator has an effect on the magnetic carrier and the reaction process and it is difficult to determine the stable operating zone of MSFB.The main research directions of MSFB in the future are proposed,including research and development of magnetic catalyst,stability criterion,mechanism of heat transfer and mass transfer,mechanism of strengthening reaction process,scale-up of reactor and design of industrial reactor.