化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2012年
9期
1903-1907
,共5页
米杰%孙国兵%潘立卫%倪长军%张磊%王树东
米傑%孫國兵%潘立衛%倪長軍%張磊%王樹東
미걸%손국병%반립위%예장군%장뢰%왕수동
燃料电池%甲醇蒸气重整%重整反应器%制氢
燃料電池%甲醇蒸氣重整%重整反應器%製氫
연료전지%갑순증기중정%중정반응기%제경
fuel cell%methanol steam reforming%reformer%hydrogen production
以解决小功率燃料电池氢源问题为目的,研制了集原料预热、甲醇水蒸气重整(MSR)、催化燃烧、水汽变换(WGS)于一体的自热式重整制氢反应器。通过条件实验考察了操作温度、甲醇气体空速、水醇比(W/M)等操作条件对重整反应的影响,并在苛刻条件下进行了稳定性研究。实验证明,反应器最大净产氢量可达90 L/h,可为百瓦级质子交换膜燃料电池提供氢源。
以解決小功率燃料電池氫源問題為目的,研製瞭集原料預熱、甲醇水蒸氣重整(MSR)、催化燃燒、水汽變換(WGS)于一體的自熱式重整製氫反應器。通過條件實驗攷察瞭操作溫度、甲醇氣體空速、水醇比(W/M)等操作條件對重整反應的影響,併在苛刻條件下進行瞭穩定性研究。實驗證明,反應器最大淨產氫量可達90 L/h,可為百瓦級質子交換膜燃料電池提供氫源。
이해결소공솔연료전지경원문제위목적,연제료집원료예열、갑순수증기중정(MSR)、최화연소、수기변환(WGS)우일체적자열식중정제경반응기。통과조건실험고찰료조작온도、갑순기체공속、수순비(W/M)등조작조건대중정반응적영향,병재가각조건하진행료은정성연구。실험증명,반응기최대정산경량가체90 L/h,가위백와급질자교환막연료전지제공경원。
A compact reactor with coupled reactant preheating,methanol steam reforming(MSR),catalytic combustion and water gas shift(WGS) was fabricated to supply hydrogen for PEMFC.The effects of reaction temperature,methanol gas space velocity(GSV) and ratio of water to methanol on reforming reaction were investigated,and the stability of the mini-reformer was also studied under various operation conditions.The yield of hydrogen reached 90L/hr,able to provide hydrogen for 100W PEMFC.