化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2012年
5期
1043-1046
,共4页
陈秋强%谢宏琴%周文%陈际帆%黄灏%曾沼汉%李晓敏
陳鞦彊%謝宏琴%週文%陳際帆%黃灝%曾沼漢%李曉敏
진추강%사굉금%주문%진제범%황호%증소한%리효민
纳米TiO2%Ce掺杂%可见光%苯酚
納米TiO2%Ce摻雜%可見光%苯酚
납미TiO2%Ce참잡%가견광%분분
nano-TiO2%cerium doped%visible light irradiation%phenol
采用Ce(NO3)3掺杂改性后的纳米TiO2粉末作为光催化剂(Ce-TiO2),研究了Ce-TiO2在可见光条件下光催化降解苯酚的过程,考察了Ce掺杂量、焙烧温度、焙烧时间、pH值以及催化剂用量等因素对苯酚溶液光催化降解过程的影响。结果表明:可见光照射下,当Ce掺杂量为1.00%、焙烧温度为700℃、焙烧时间为3 h、反应溶液pH值为5、催化剂投加量为1.0 g/L时,苯酚的去除率达到最佳,为35.8%。
採用Ce(NO3)3摻雜改性後的納米TiO2粉末作為光催化劑(Ce-TiO2),研究瞭Ce-TiO2在可見光條件下光催化降解苯酚的過程,攷察瞭Ce摻雜量、焙燒溫度、焙燒時間、pH值以及催化劑用量等因素對苯酚溶液光催化降解過程的影響。結果錶明:可見光照射下,噹Ce摻雜量為1.00%、焙燒溫度為700℃、焙燒時間為3 h、反應溶液pH值為5、催化劑投加量為1.0 g/L時,苯酚的去除率達到最佳,為35.8%。
채용Ce(NO3)3참잡개성후적납미TiO2분말작위광최화제(Ce-TiO2),연구료Ce-TiO2재가견광조건하광최화강해분분적과정,고찰료Ce참잡량、배소온도、배소시간、pH치이급최화제용량등인소대분분용액광최화강해과정적영향。결과표명:가견광조사하,당Ce참잡량위1.00%、배소온도위700℃、배소시간위3 h、반응용액pH치위5、최화제투가량위1.0 g/L시,분분적거제솔체도최가,위35.8%。
Mineralization of phenol was investigated under visible light irradiation by using the catalyst cerium doped nano-TiO2 ( named as Ce-TiO2 ). Degradation of phenol in different reaction systems was discussed, and the influences of reaction conditions, such as phenol concentration, solution pH, catalyst dosage and reaction temperature were also evaluated. The catalytic results showed that 35.8% TOC removal of phenol were achieved under visible irradiation at a reaction condition of cerium doped amount of 1.00%, calcination temperature at 700 ℃, calcination time for 3 h, pH 5 and 1.0 g/L catalyst dosage