化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2012年
6期
1274-1279
,共6页
李园园%陈少华%张召基%石建稳%汤凤霞
李園園%陳少華%張召基%石建穩%湯鳳霞
리완완%진소화%장소기%석건은%탕봉하
丝瓜络%KOH%活性炭
絲瓜絡%KOH%活性炭
사과락%KOH%활성탄
Luffa cylindrical sponge%KOH%activated carbon
为了探讨以丝瓜络为原料制备高比表面积活性炭的最佳条件,通过设计正交实验,研究了碱炭比、活化温度、活化时间和升温速率等因素对KOH活化丝瓜络制备活性炭性能的影响。结果表明:KOH活化丝瓜络制备活性炭的最佳条件为:碱炭比为4、活化温度800℃,活化时间30 min,升温速率10℃/min。在此条件下制备的活性炭为多孔、非晶型的无定形碳,具有高的比表面积(3545 m2/g)和强的吸附性能,其碘值和亚甲基蓝值分别达到2926 mg/g和528.58 mg/g;为丝瓜络的高值化利用提供了一条有价值的途径。
為瞭探討以絲瓜絡為原料製備高比錶麵積活性炭的最佳條件,通過設計正交實驗,研究瞭堿炭比、活化溫度、活化時間和升溫速率等因素對KOH活化絲瓜絡製備活性炭性能的影響。結果錶明:KOH活化絲瓜絡製備活性炭的最佳條件為:堿炭比為4、活化溫度800℃,活化時間30 min,升溫速率10℃/min。在此條件下製備的活性炭為多孔、非晶型的無定形碳,具有高的比錶麵積(3545 m2/g)和彊的吸附性能,其碘值和亞甲基藍值分彆達到2926 mg/g和528.58 mg/g;為絲瓜絡的高值化利用提供瞭一條有價值的途徑。
위료탐토이사과락위원료제비고비표면적활성탄적최가조건,통과설계정교실험,연구료감탄비、활화온도、활화시간화승온속솔등인소대KOH활화사과락제비활성탄성능적영향。결과표명:KOH활화사과락제비활성탄적최가조건위:감탄비위4、활화온도800℃,활화시간30 min,승온속솔10℃/min。재차조건하제비적활성탄위다공、비정형적무정형탄,구유고적비표면적(3545 m2/g)화강적흡부성능,기전치화아갑기람치분별체도2926 mg/g화528.58 mg/g;위사과락적고치화이용제공료일조유개치적도경。
In this study,activated carbon with high surface area was prepared from Luffa cylindrical sponge by KOH activation.The effects of KOH/C ratio,activation temperature,activation time and heating rate on the properties of as-prepared activated carbons were investigated by means of orthogonal test design.Results showed that the optimal condition is following:KOH/C weight ratio 4, activation temperature 800 ℃,activation time 30 min,and heating rate 10 ℃/min.The as-prepared activated carbon is porous and amorphous,which has high surface area of 3545 m2/g,and the iodine and methylene blue adsorption value reached to 2926 mg/g and 528.58 mg/g,respectively.This study presents a valuable pathway for comprehensive utilization of Luffa cylindrical sponge.