CAJ | 학술논문

简要介绍了生产羟胺（盐）的拉西法、硝酸根离子还原法等工业方法,以及一步合成羟胺的最新研究进展;概述了羟胺（盐）在合成环己酮肟、制备羟胺-O-磺酸等传统应用领域,以及在合成芳香烃胺类、芳香烃酚类化合物等清洁安全化工过程中的最新应用。在此基础上,指出随着羟胺的用途不断扩展,在温和的反应条件下、清洁高效的一步合成羟胺（盐）是今后的研究热点。
간요개소료생산간알（염）적랍서법、초산근리자환원법등공업방법,이급일보합성간알적최신연구진전;개술료간알（염）재합성배기동우、제비간알-O-광산등전통응용영역,이급재합성방향경알류、방향경분류화합물등청길안전화공과정중적최신응용。재차기출상,지출수착간알적용도불단확전,재온화적반응조건하、청길고효적일보합성간알（염）시금후적연구열점。
The industrial routes,such as Raschig synthesis,reduction of nitrous acid,and one-pot synthesis for preparation of hydroxylamine（salts） are reviewed.Furthermore,the new application of hydroxylamine to synthesis of aniline and phenol derivatives,along with traditional uses of hydroxylamine（salts） for the production of cyclohexanone oxime and hydroxylamine-O-sulfonic acid,is also introduced.With increasing demand for hydroxylamine,future trend on hydroxylamine（salts） synthesis is proposed based on the above discussions,i.e.one-pot synthesis of hydroxylamine can be realized efficiently under mild reaction conditions.